{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,13]],"date-time":"2026-01-13T09:08:09Z","timestamp":1768295289001,"version":"3.49.0"},"reference-count":107,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2015,3,3]],"date-time":"2015-03-03T00:00:00Z","timestamp":1425340800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2015,4,7]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A new amino\u2010functionalized strontium\u2013carboxylate\u2010based metal\u2013organic framework (MOF) has been synthesized that undergoes single crystal to single crystal (SC\u2010to\u2010SC) transformation upon desolvation. Both structures have been characterized by single\u2010crystal X\u2010ray analysis. The desolvated structure shows an interesting 3D porous structure with pendent \uf8ffNH<jats:sub>2<\/jats:sub> groups inside the pore wall, whereas the solvated compound possesses a nonporous structure with DMF molecules on the metal centers. The amino group was postmodified through Schiff base condensation by pyridine\u20102\u2010carboxaldehyde and palladium was anchored on that site. The modified framework has been utilized for the Suzuki cross\u2010coupling reaction. The compound shows high activity towards the C\uf8ffC cross\u2010coupling reaction with good yields and turnover frequencies. Gas adsorption studies showed that the desolvated compound had permanent porosity and was microporous in nature with a BET surface area of 2052\u2005m<jats:sup>2<\/jats:sup>\u2009g<jats:sup>\u22121<\/jats:sup>. The material also possesses good CO<jats:sub>2<\/jats:sub> (8\u2005wt\u2009%) and H<jats:sub>2<\/jats:sub> (1.87\u2005wt\u2009%) adsorption capabilities.<\/jats:p>","DOI":"10.1002\/chem.201405684","type":"journal-article","created":{"date-parts":[[2015,3,3]],"date-time":"2015-03-03T04:47:42Z","timestamp":1425358062000},"page":"5962-5971","source":"Crossref","is-referenced-by-count":33,"title":["Single Crystal to Single Crystal (SC\u2010to\u2010SC) Transformation from a Nonporous to Porous Metal\u2013Organic Framework and Its Application Potential in Gas Adsorption and Suzuki Coupling Reaction through Postmodification"],"prefix":"10.1002","volume":"21","author":[{"given":"Rupam","family":"Sen","sequence":"first","affiliation":[]},{"given":"Debraj","family":"Saha","sequence":"additional","affiliation":[]},{"given":"Subratanath","family":"Koner","sequence":"additional","affiliation":[]},{"given":"Paula","family":"Brand\u00e3o","sequence":"additional","affiliation":[]},{"given":"Zhi","family":"Lin","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2015,3,3]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr200190s"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b313997m"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr300014x"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9003924"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/b807080f"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3ra42105h"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/cplu.201402123"},{"key":"e_1_2_6_9_2","unstructured":"\u00a0"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/b804757j"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1039\/B718581M"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/b918554b"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/B814614D"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/c002372h"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic802050j"},{"key":"e_1_2_6_16_2","unstructured":"\u00a0"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja104035j"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja903251e"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1038\/nmat2808"},{"key":"e_1_2_6_20_2","unstructured":"\u00a0"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200300636"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1230444"},{"key":"e_1_2_6_23_2","unstructured":"\u00a0"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1595\/147106711X558301"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1039\/B814973A"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200900139"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2005.02.026"},{"key":"e_1_2_6_28_2","unstructured":"\u00a0"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00039a007"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(98)01055-9"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198605081"},{"key":"e_1_2_6_31_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19860980605"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja026975w"},{"key":"e_1_2_6_33_2","unstructured":"\u00a0"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200806063"},{"key":"e_1_2_6_34_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200806063"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2011.03.014"},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0cp02394a"},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.2174\/1874478811104010001"},{"key":"e_1_2_6_38_2","unstructured":"\u00a0"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00003J"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201106615"},{"key":"e_1_2_6_40_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201106615"},{"key":"e_1_2_6_41_2","unstructured":"\u00a0"},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr0505674"},{"key":"e_1_2_6_43_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr010361c"},{"key":"e_1_2_6_44_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2jm15563j"},{"key":"e_1_2_6_45_2","doi-asserted-by":"publisher","DOI":"10.1038\/35010088"},{"key":"e_1_2_6_46_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja074366o"},{"key":"e_1_2_6_47_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs35047e"},{"key":"e_1_2_6_48_2","doi-asserted-by":"publisher","DOI":"10.1021\/cs400094x"},{"key":"e_1_2_6_49_2","unstructured":"\u00a0"},{"key":"e_1_2_6_50_2","doi-asserted-by":"publisher","DOI":"10.1021\/la902945x"},{"key":"e_1_2_6_51_2","doi-asserted-by":"publisher","DOI":"10.1021\/la7040086"},{"key":"e_1_2_6_52_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201000937"},{"key":"e_1_2_6_53_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201100118"},{"key":"e_1_2_6_54_2","unstructured":"\u00a0"},{"key":"e_1_2_6_55_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201102953"},{"key":"e_1_2_6_56_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2dt00057a"},{"key":"e_1_2_6_57_2","doi-asserted-by":"publisher","DOI":"10.1021\/cg500498k"},{"key":"e_1_2_6_58_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2004.09.049"},{"key":"e_1_2_6_59_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2009.12.021"},{"key":"e_1_2_6_60_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01269a023"},{"key":"e_1_2_6_61_2","unstructured":"\u00a0"},{"key":"e_1_2_6_62_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja401429x"},{"key":"e_1_2_6_63_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr2003272"},{"key":"e_1_2_6_64_2","unstructured":"\u00a0"},{"key":"e_1_2_6_65_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja4004766"},{"key":"e_1_2_6_66_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja300034j"},{"key":"e_1_2_6_67_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja909169x"},{"key":"e_1_2_6_68_2","doi-asserted-by":"publisher","DOI":"10.1080\/10610278.2010.523119"},{"key":"e_1_2_6_69_2","doi-asserted-by":"publisher","DOI":"10.1039\/b910228k"},{"key":"e_1_2_6_70_2","doi-asserted-by":"publisher","DOI":"10.1039\/b911481e"},{"key":"e_1_2_6_71_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10450-008-9137-6"},{"key":"e_1_2_6_72_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0570032"},{"key":"e_1_2_6_73_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp311512q"},{"key":"e_1_2_6_74_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja056639q"},{"key":"e_1_2_6_75_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr200274s"},{"key":"e_1_2_6_76_2","doi-asserted-by":"publisher","DOI":"10.1038\/35104634"},{"key":"e_1_2_6_77_2","unstructured":"\u00a0"},{"key":"e_1_2_6_78_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0cc01986k"},{"key":"e_1_2_6_79_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.200700489"},{"key":"e_1_2_6_80_2","doi-asserted-by":"publisher","DOI":"10.1039\/b815568b"},{"key":"e_1_2_6_81_2","doi-asserted-by":"publisher","DOI":"10.1039\/b704098a"},{"key":"e_1_2_6_82_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2gc35302d"},{"key":"e_1_2_6_83_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.200800304"},{"key":"e_1_2_6_84_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic062183h"},{"key":"e_1_2_6_85_2","unstructured":"\u00a0"},{"key":"e_1_2_6_86_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(02)01132-2"},{"key":"e_1_2_6_87_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm8020337"},{"key":"e_1_2_6_88_2","unstructured":"\u00a0"},{"key":"e_1_2_6_89_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo050801q"},{"key":"e_1_2_6_90_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2010.07.076"},{"key":"e_1_2_6_91_2","unstructured":"\u00a0"},{"key":"e_1_2_6_92_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2008.11.060"},{"key":"e_1_2_6_93_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2007.02.044"},{"key":"e_1_2_6_94_2","doi-asserted-by":"publisher","DOI":"10.1039\/b919175e"},{"key":"e_1_2_6_95_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2004.11.006"},{"key":"e_1_2_6_96_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo030302u"},{"key":"e_1_2_6_97_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2007.07.005"},{"key":"e_1_2_6_98_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2007.09.007"},{"key":"e_1_2_6_99_2","doi-asserted-by":"publisher","DOI":"10.1039\/b211742h"},{"key":"e_1_2_6_100_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2007.06.004"},{"key":"e_1_2_6_101_2","doi-asserted-by":"publisher","DOI":"10.1002\/cssc.200900006"},{"key":"e_1_2_6_102_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2007.07.027"},{"key":"e_1_2_6_103_2","doi-asserted-by":"publisher","DOI":"10.1021\/om900209j"},{"key":"e_1_2_6_104_2","doi-asserted-by":"crossref","first-page":"179","DOI":"10.1016\/S0926-860X(02)00285-5","volume":"236","author":"Corma A.","year":"2002","journal-title":"Appl. Catal. A"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fchem.201405684","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.201405684","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T18:53:40Z","timestamp":1760295220000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.201405684"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2015,3,3]]},"references-count":107,"journal-issue":{"issue":"15","published-print":{"date-parts":[[2015,4,7]]}},"alternative-id":["10.1002\/chem.201405684"],"URL":"https:\/\/doi.org\/10.1002\/chem.201405684","archive":["Portico"],"relation":{},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2015,3,3]]}}}