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This reaction is an environmentally benign process implementing inexpensive, earth\u2010abundant non\u2010precious metal catalysts, and is based on the acceptorless alcohol dehydrogenation concept. A range of alcohols and amines including both aromatic and aliphatic substrates were efficiently converted in good to excellent isolated yields. Although in the case of Mn selectively imines were obtained, with Fe\u2014exclusively monoalkylated amines were formed. These reactions proceed under base\u2010free conditions and required the addition of molecular sieves.<\/jats:p>","DOI":"10.1002\/chem.201603148","type":"journal-article","created":{"date-parts":[[2016,7,5]],"date-time":"2016-07-05T03:34:32Z","timestamp":1467689672000},"page":"12316-12320","source":"Crossref","is-referenced-by-count":236,"title":["Divergent Coupling of Alcohols and Amines Catalyzed by Isoelectronic Hydride Mn<sup>I<\/sup> and Fe<sup>II<\/sup> PNP Pincer Complexes"],"prefix":"10.1002","volume":"22","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-8969-7902","authenticated-orcid":false,"given":"Matthias","family":"Mastalir","sequence":"first","affiliation":[{"name":"Institute of Applied Synthetic Chemistry Vienna University of Technology  Getreidemarkt 9 1060 Wien Austria"}]},{"given":"Mathias","family":"Glatz","sequence":"additional","affiliation":[{"name":"Institute of Applied Synthetic Chemistry Vienna University of Technology  Getreidemarkt 9 1060 Wien Austria"}]},{"given":"Nikolaus","family":"Gorgas","sequence":"additional","affiliation":[{"name":"Institute of Applied Synthetic Chemistry Vienna University of Technology  Getreidemarkt 9 1060 Wien Austria"}]},{"given":"Berthold","family":"St\u00f6ger","sequence":"additional","affiliation":[{"name":"Institute of Chemical Technologies and Analytics Vienna University of Technology  Getreidemarkt 9 1060 Wien Austria"}]},{"given":"Ernst","family":"Pittenauer","sequence":"additional","affiliation":[{"name":"Institute of Chemical Technologies and Analytics Vienna University of Technology  Getreidemarkt 9 1060 Wien Austria"}]},{"given":"G\u00fcnter","family":"Allmaier","sequence":"additional","affiliation":[{"name":"Institute of Chemical Technologies and Analytics Vienna University of Technology  Getreidemarkt 9 1060 Wien Austria"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5841-3519","authenticated-orcid":false,"given":"Luis F.","family":"Veiros","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural Instituto Superior T\u00e9cnico Universidade de Lisboa  Av. 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