{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,26]],"date-time":"2026-02-26T15:04:49Z","timestamp":1772118289538,"version":"3.50.1"},"reference-count":130,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2025,2,17]],"date-time":"2025-02-17T00:00:00Z","timestamp":1739750400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100015072","name":"Institute for Advanced Study, Technische Universit\u00e4t M\u00fcnchen","doi-asserted-by":"publisher","award":["Hans Fischer Senior Fellow"],"award-info":[{"award-number":["Hans Fischer Senior Fellow"]}],"id":[{"id":"10.13039\/501100015072","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100018694","name":"HORIZON EUROPE Marie Sklodowska-Curie Actions","doi-asserted-by":"publisher","award":["764837"],"award-info":[{"award-number":["764837"]}],"id":[{"id":"10.13039\/100018694","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Chemistry A European J"],"published-print":{"date-parts":[[2025,4]]},"abstract":"<jats:title>Abstract<\/jats:title>\n                  <jats:p>\n                    Metal coordination compounds are currently a focus of research in developing new photosensitizers for materials and medicinal applications. As an abundant element in the earth's crust aluminum is a suitable target element. However, only limited studies are available on its use in photoactive systems. We now report the facile preparation of a library of homoleptic tris(dipyrrinato)aluminum(III) [AL(DIPY)\n                    <jats:sub>3<\/jats:sub>\n                    ] complexes. The majority of complexes was characterized by single crystal X\u2010ray analysis and their photophysical properties upon photoexcitation and their tendency to react with the molecular oxygen of the microenvironment and generate singlet oxygen \u2010 in polar and non\u2010polar environment was investigated. These studies are complemented by density functional theory (DFT) calculations to assess the possible electronic distribution on the frontier molecular orbitals within the complexes. As a result of charge transfer states, long\u2010lived triplet excited states were formed and allowed for singlet oxygen generation. An initial screening of the AL(DIPY)\n                    <jats:sub>3<\/jats:sub>\n                    complexes\n                    <jats:italic>via in\u2005vitro<\/jats:italic>\n                    phototoxicity studies against a mouse colon carcinoma cell line (CT26) was promising as these complexes were able to trigger cell death upon irradiation at nanomolar and micromolar concentrations. The results highlight the potential of aluminum dipyrrin complexes as a broadly applicable class of photosensitizers.\n                  <\/jats:p>","DOI":"10.1002\/chem.202404777","type":"journal-article","created":{"date-parts":[[2025,2,11]],"date-time":"2025-02-11T00:57:24Z","timestamp":1739235444000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Aluminum Photosensitizers on Trial: Synthesis, Crystal Structures, Photophysical and Photobiological Properties of Tris(Dipyrrinato)Aluminum(III) Complexes with Long\u2010Lived Triplet States"],"prefix":"10.1002","volume":"31","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5356-3435","authenticated-orcid":false,"given":"Zoi","family":"Melissari","sequence":"first","affiliation":[{"name":"Medicinal Chemistry, Trinity Translational Medicine Institute, St. James's Hospital, Trinity College Dublin The University of Dublin  Dublin D08W9RT Ireland"},{"name":"Van \u2018t Hoff Institute for Molecular Sciences University of Amsterdam  P.O. Box 941571090 GD Amsterdam The Netherlands"}]},{"given":"Brendan","family":"Twamley","sequence":"additional","affiliation":[{"name":"School of Chemistry, Trinity College Dublin The University of Dublin  Dublin 2 Ireland"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0624-8819","authenticated-orcid":false,"given":"L\u00edgia C.","family":"Gomes\u2010da\u2010Silva","sequence":"additional","affiliation":[{"name":"CQC-IMS \u2013 Coimbra Chemistry Center \u2013 Institute of Molecular Sciences University of Coimbra  Coimbra 3004-535 Portugal"}]},{"given":"John E.","family":"O'Brien","sequence":"additional","affiliation":[{"name":"School of Chemistry, Trinity College Dublin The University of Dublin  Dublin 2 Ireland"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9339-7259","authenticated-orcid":false,"given":"F\u00e1bio A.","family":"Schaberle","sequence":"additional","affiliation":[{"name":"CQC-IMS \u2013 Coimbra Chemistry Center \u2013 Institute of Molecular Sciences University of Coimbra  Coimbra 3004-535 Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4694-5566","authenticated-orcid":false,"given":"Christopher J.","family":"Kingsbury","sequence":"additional","affiliation":[{"name":"School of Chemistry, Chair of Organic Chemistry, Trinity Biomedical Sciences Institute, Trinity College Dublin The University of Dublin  152\u2013160 Pearse Street Dublin D02R590 Ireland"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9490-6182","authenticated-orcid":false,"given":"Ren\u00e9 M.","family":"Williams","sequence":"additional","affiliation":[{"name":"Van \u2018t Hoff Institute for Molecular Sciences University of Amsterdam  P.O. Box 941571090 GD Amsterdam The Netherlands"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7467-1654","authenticated-orcid":false,"given":"Mathias O.","family":"Senge","sequence":"additional","affiliation":[{"name":"Medicinal Chemistry, Trinity Translational Medicine Institute, St. James's Hospital, Trinity College Dublin The University of Dublin  Dublin D08W9RT Ireland"},{"name":"Institute for Advanced Study (TUM-IAS) Technical University of Munich  Lichtenbergstrasse 2a D-85748 Garching Germany"}]}],"member":"311","published-online":{"date-parts":[[2025,2,17]]},"reference":[{"key":"e_1_2_8_1_1","unstructured":"H. Fischer H. Orth Die Chemie des Pyrrols Vol. I Akademische Verlagsgesellschaft Leipzig 1934."},{"key":"e_1_2_8_2_1","unstructured":"\u00a0"},{"key":"e_1_2_8_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr050052c"},{"key":"e_1_2_8_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/c3dt50493j"},{"key":"e_1_2_8_5_2","doi-asserted-by":"publisher","DOI":"10.3390\/molecules27206967"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/D1CS00609F"},{"key":"e_1_2_8_7_1","unstructured":"\u00a0"},{"key":"e_1_2_8_8_2","doi-asserted-by":"publisher","DOI":"10.1093\/jnci\/90.12.889"},{"key":"e_1_2_8_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1572-1000(05)00007-4"},{"key":"e_1_2_8_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/c9pp00211a"},{"key":"e_1_2_8_11_1","unstructured":"\u00a0"},{"key":"e_1_2_8_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/jlac.19687180119"},{"key":"e_1_2_8_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/C2CS35216H"},{"key":"e_1_2_8_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201500682"},{"key":"e_1_2_8_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr078381n"},{"key":"e_1_2_8_16_1","unstructured":"\u00a0"},{"key":"e_1_2_8_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic500326u"},{"key":"e_1_2_8_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic061581h"},{"key":"e_1_2_8_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic7016159"},{"key":"e_1_2_8_20_2","doi-asserted-by":"publisher","DOI":"10.1039\/C8DT03059F"},{"key":"e_1_2_8_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202004776"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b03235"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja038763k"},{"key":"e_1_2_8_24_1","unstructured":"\u00a0"},{"key":"e_1_2_8_25_2","doi-asserted-by":"publisher","DOI":"10.1038\/nchem.1535"},{"key":"e_1_2_8_26_2","doi-asserted-by":"crossref","unstructured":"C. Ni X. Ma Z. Yang H.\u2005W. Roesky Eur. J. Inorg. Chem.2022 e202100929.","DOI":"10.1002\/ejic.202100929"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099-1409(199908\/10)3:6\/7<424::AID-JPP151>3.0.CO;2-K"},{"key":"e_1_2_8_28_1","unstructured":"\u00a0"},{"key":"e_1_2_8_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/om500730g"},{"key":"e_1_2_8_30_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6DT02449A"},{"key":"e_1_2_8_31_1","doi-asserted-by":"crossref","unstructured":"C. Ikeda S. Ueda T. Nabeshima Chem. Commun.2009 2544\u20132546.","DOI":"10.1039\/b820141b"},{"key":"e_1_2_8_32_1","unstructured":"\u00a0"},{"key":"e_1_2_8_33_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.47.3021"},{"key":"e_1_2_8_34_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.47.458"},{"key":"e_1_2_8_35_1","unstructured":"S. Toguchi H. Ishikawa Y. Morioka A. Oda (Samsung SDI Co.) US 6 759 144 B2 2004."},{"key":"e_1_2_8_36_1","unstructured":"\u00a0"},{"key":"e_1_2_8_37_2","doi-asserted-by":"publisher","DOI":"10.1139\/v96-245"},{"key":"e_1_2_8_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic034559m"},{"key":"e_1_2_8_39_2","doi-asserted-by":"publisher","DOI":"10.1351\/pac199668071373"},{"key":"e_1_2_8_40_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(97)05700-9"},{"key":"e_1_2_8_41_1","unstructured":"\u00a0"},{"key":"e_1_2_8_42_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b00551"},{"key":"e_1_2_8_43_2","doi-asserted-by":"publisher","DOI":"10.1039\/C7CP08472B"},{"key":"e_1_2_8_44_2","doi-asserted-by":"publisher","DOI":"10.1002\/cptc.201800020"},{"key":"e_1_2_8_45_2","doi-asserted-by":"publisher","DOI":"10.1002\/cptc.202000191"},{"key":"e_1_2_8_46_2","doi-asserted-by":"publisher","DOI":"10.1142\/S1088424622500328"},{"key":"e_1_2_8_47_1","unstructured":"A.\u2005W. Apblett inEncycl. Inorg. Bioinorg. Chem. John Wiley & Sons Ltd 2012 pp. 1\u201319."},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(01)95429-2"},{"key":"e_1_2_8_49_1","doi-asserted-by":"crossref","unstructured":"H. Sugimoto M. Muto T. Tanaka A. Osuka Eur. J. Org. Chem.2011 71\u201377.","DOI":"10.1002\/ejoc.201001188"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(02)01176-3"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.202401559"},{"key":"e_1_2_8_52_1","unstructured":"\u00a0"},{"key":"e_1_2_8_53_2","doi-asserted-by":"crossref","unstructured":"S.\u2005G. Telfer J.\u2005D. Wuest Chem. Commun.2007 3166\u2013316;","DOI":"10.1039\/b705212j"},{"key":"e_1_2_8_54_2","doi-asserted-by":"publisher","DOI":"10.1039\/B912332F"},{"key":"e_1_2_8_55_1","unstructured":"\u00a0"},{"key":"e_1_2_8_56_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.pdpdt.2010.12.001"},{"key":"e_1_2_8_57_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4CC09494H"},{"key":"e_1_2_8_58_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.biomaterials.2020.119827"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1351\/pac196511030371"},{"key":"e_1_2_8_60_1","unstructured":"Bosnich summarized the analysis of the exciton coupling effect in a coherent way for octahedral configurations of metal complexes and this justification can be applied in the case of the tris(dipyrrinato)aluminum(III) complexes:"},{"key":"e_1_2_8_61_2","doi-asserted-by":"publisher","DOI":"10.1021\/ar50021a002"},{"key":"e_1_2_8_62_2","doi-asserted-by":"publisher","DOI":"10.1039\/c0dt01226b"},{"key":"e_1_2_8_63_1","unstructured":"\u00a0"},{"key":"e_1_2_8_64_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp8022524"},{"key":"e_1_2_8_65_2","doi-asserted-by":"publisher","DOI":"10.1039\/B813638F"},{"key":"e_1_2_8_66_1","doi-asserted-by":"crossref","unstructured":"J.\u2005E. Fergusson C.\u2005A. Ramsay J. Chem. Soc.1965 5222\u20135225.","DOI":"10.1039\/jr9650005222"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic0352295"},{"key":"e_1_2_8_68_1","unstructured":"\u00a0"},{"key":"e_1_2_8_69_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.37.785"},{"key":"e_1_2_8_70_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.464913"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5NJ03339J"},{"key":"e_1_2_8_72_1","doi-asserted-by":"crossref","unstructured":"J.\u2005M. Sutton E. Rogerson C.\u2005J. Wilson A.\u2005E. Sparke S.\u2005J. Archibald R.\u2005W. Boyle Chem. Commun.2004 1328\u20131329.","DOI":"10.1039\/b404147j"},{"key":"e_1_2_8_73_1","unstructured":"\u00a0"},{"key":"e_1_2_8_74_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.8b01237"},{"key":"e_1_2_8_75_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp506855t"},{"key":"e_1_2_8_76_2","doi-asserted-by":"publisher","DOI":"10.1039\/C6RA27547H"},{"key":"e_1_2_8_77_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201907856"},{"key":"e_1_2_8_78_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.5145052"},{"key":"e_1_2_8_79_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpcc.9b06170"},{"key":"e_1_2_8_80_1","doi-asserted-by":"crossref","unstructured":"M. Montalti A. Credi L. Prodi M.\u2005T. Gandolfi Handbook of Photochemistry CRC\/Taylor & Francis Boca Raton 2006.","DOI":"10.1201\/9781420015195"},{"key":"e_1_2_8_81_1","unstructured":"\u00a0"},{"key":"e_1_2_8_82_2","doi-asserted-by":"publisher","DOI":"10.1039\/c9pp00399a"},{"key":"e_1_2_8_83_2","doi-asserted-by":"publisher","DOI":"10.1111\/j.1751-1097.1999.tb08240.x"},{"key":"e_1_2_8_84_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(02)00034-6"},{"key":"e_1_2_8_85_1","doi-asserted-by":"publisher","DOI":"10.1039\/b926014p"},{"key":"e_1_2_8_86_1","doi-asserted-by":"publisher","DOI":"10.1039\/9781782622208-00023"},{"key":"e_1_2_8_87_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.1c01850"},{"key":"e_1_2_8_88_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.8b01225"},{"key":"e_1_2_8_89_1","unstructured":"\u00a0"},{"key":"e_1_2_8_90_2","doi-asserted-by":"publisher","DOI":"10.1046\/j.1432-1327.2000.01606.x"},{"key":"e_1_2_8_91_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-1-61779-108-6_5"},{"key":"e_1_2_8_92_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pdpdt.2018.06.009"},{"key":"e_1_2_8_93_1","unstructured":"\u00a0"},{"key":"e_1_2_8_94_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00211"},{"key":"e_1_2_8_95_2","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c05844"},{"key":"e_1_2_8_96_1","unstructured":"\u00a0"},{"key":"e_1_2_8_97_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja408426z"},{"key":"e_1_2_8_98_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic5002368"},{"key":"e_1_2_8_99_1","doi-asserted-by":"publisher","DOI":"10.3109\/10408444.2014.934439"},{"key":"e_1_2_8_100_1","unstructured":"\u00a0"},{"key":"e_1_2_8_101_2","unstructured":"WaveMetrics Inc IgorPro Version 7.0.8.1 1988\u20132018 Lake Oswego Oregon USA;"},{"key":"e_1_2_8_102_2","unstructured":"OriginPro 8.5 OriginLab Corporation Northampton MA USA;"},{"key":"e_1_2_8_103_2","unstructured":"F. Menges Spectragryph-Optical Spectroscopy Software Version 1.2.13 2016\u20132019 Oberstdorf Germany Http:\/\/Www.Effemm2.de\/Spectragryph\/."},{"key":"e_1_2_8_104_1","unstructured":"\u00a0"},{"key":"e_1_2_8_105_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(01)89282-6"},{"key":"e_1_2_8_106_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo982015"},{"key":"e_1_2_8_107_2","doi-asserted-by":"publisher","DOI":"10.1021\/op034083q"},{"key":"e_1_2_8_108_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8OB00272J"},{"key":"e_1_2_8_109_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.201100642"},{"key":"e_1_2_8_110_1","unstructured":"\u00a0"},{"key":"e_1_2_8_111_2","unstructured":"Gaussian 16 Revision C.01 M.\u2005J. Frisch G.\u2005W. Trucks H.\u2005B. Schlegel G.\u2005E. Scuseria M.\u2005A. Robb J.\u2005R. Cheeseman G. Scalmani V. Barone G.\u2005A. Petersson H. Nakatsuji X. Li M. Caricato A.\u2005V. Marenich J. Bloino B.\u2005G. Janesko R. Gomperts B. Mennucci H.\u2005P. Hratchian J.\u2005V. Ortiz A.\u2005F. Izmaylov J.\u2005L. Sonnenberg D. Williams-Young F. Ding F. Lipparini F. Egidi J. Goings B. Peng A. Petrone T. Henderson D. Ranasinghe V.\u2005G. Zakrzewski J. Gao N. Rega G. Zheng W. Liang M. Hada M. Ehara K. Toyota R. Fukuda J. Hasegawa M. Ishida T. Nakajima Y. Honda O. Kitao H. Nakai T. Vreven K. Throssell J.\u2005A. Montgomery \u2005Jr. J.\u2005E. Peralta F. Ogliaro M.\u2005J. Bearpark J.\u2005J. Heyd E.\u2005N. Brothers K.\u2005N. Kudin V.\u2005N. Staroverov T.\u2005A. Keith R. Kobayashi J. Normand K. Raghavachari A.\u2005P. Rendell J.\u2005C. Burant S.\u2005S. Iyengar J. Tomasi M. Cossi J.\u2005M. Millam M. Klene C. Adamo R. Cammi J.\u2005W. Ochterski R.\u2005L. Martin K. Morokuma O. Farkas J.\u2005B. Foresman D.\u2005J. Fox Gaussian Inc. Wallingford CT 2019;"},{"key":"e_1_2_8_112_2","doi-asserted-by":"crossref","unstructured":"M.\u2005D. Hanwell D.\u2005E. Curtis D.\u2005C. Lonie T. Vandermeersch E. Zurek G.\u2005R. Hutchison J. Cheminf.2012 4 1\u201317 Version 1.2.0;","DOI":"10.1186\/1758-2946-4-17"},{"key":"e_1_2_8_113_2","doi-asserted-by":"crossref","unstructured":"A.\u2005R. Allouche J. Comput. Chem.2011 32 174\u2013182 Version 2.5.0;","DOI":"10.1002\/jcc.21600"},{"key":"e_1_2_8_114_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.37.785"},{"key":"e_1_2_8_115_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.464913"},{"key":"e_1_2_8_116_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic061581h"},{"key":"e_1_2_8_117_1","unstructured":"\u00a0"},{"key":"e_1_2_8_118_2","unstructured":"Bruker APEX3\u2005V2017.3-0 Bruker AXS Inc. Madison Wisconsin (USA) 2017;"},{"key":"e_1_2_8_119_2","doi-asserted-by":"publisher","DOI":"10.1107\/S1600576714022985"},{"key":"e_1_2_8_120_2","doi-asserted-by":"publisher","DOI":"10.1107\/S2053273314026370"},{"key":"e_1_2_8_121_2","doi-asserted-by":"publisher","DOI":"10.1107\/S2053229614024218"},{"key":"e_1_2_8_122_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889808042726"},{"key":"e_1_2_8_123_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(02)01176-3"},{"key":"e_1_2_8_124_2","doi-asserted-by":"publisher","DOI":"10.1107\/S2056989019016244"},{"key":"e_1_2_8_125_2","doi-asserted-by":"publisher","DOI":"10.1107\/S090744490804362X"},{"key":"e_1_2_8_126_2","doi-asserted-by":"publisher","DOI":"10.1107\/S2053229614024929"},{"key":"e_1_2_8_127_1","unstructured":"\u00a0"},{"key":"e_1_2_8_128_2","doi-asserted-by":"publisher","DOI":"10.1039\/D4SC01670J"},{"key":"e_1_2_8_129_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202403754"},{"key":"e_1_2_8_129_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202403754"}],"container-title":["Chemistry \u2013 A European Journal"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/chem.202404777","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T17:40:11Z","timestamp":1760290811000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/chem.202404777"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,2,17]]},"references-count":130,"journal-issue":{"issue":"19","published-print":{"date-parts":[[2025,4]]}},"alternative-id":["10.1002\/chem.202404777"],"URL":"https:\/\/doi.org\/10.1002\/chem.202404777","archive":["Portico"],"relation":{"has-preprint":[{"id-type":"doi","id":"10.26434\/chemrxiv-2024-ftq9n","asserted-by":"object"}]},"ISSN":["0947-6539","1521-3765"],"issn-type":[{"value":"0947-6539","type":"print"},{"value":"1521-3765","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,2,17]]},"assertion":[{"value":"2024-12-29","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-02-17","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202404777"}}