{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,26]],"date-time":"2026-01-26T21:24:21Z","timestamp":1769462661960,"version":"3.49.0"},"reference-count":31,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2016,12,30]],"date-time":"2016-12-30T00:00:00Z","timestamp":1483056000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["ChemPhysChem"],"published-print":{"date-parts":[[2017,2,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>This study highlights that Fe additives offer better catalytic properties than carbon, Fe\u2212C (iron carbide\/carbon composites), and Fe\u2010Mg (Mg<jats:sub>2<\/jats:sub>FeH<jats:sub>6<\/jats:sub>) additives for the low\u2010temperature dehydrogenation of magnesium hydride. The in\u2005situ X\u2010ray diffraction measurements prove the formation of a Mg<jats:sub>2<\/jats:sub>FeH<jats:sub>6<\/jats:sub> phase in iron additive loaded MgH<jats:sub>2<\/jats:sub>. Nonetheless, differential scanning calorimetry data suggest that this Mg<jats:sub>2<\/jats:sub>FeH<jats:sub>6<\/jats:sub> phase does not have any influence on dehydrogenation properties of MgH<jats:sub>2<\/jats:sub>. On the other hand, the composite system Mg<jats:sub>2<\/jats:sub>FeH<jats:sub>6<\/jats:sub>\/MgH<jats:sub>2<\/jats:sub> shows significantly improved dehydrogenation properties even in absence of further additives. It is suggested that the improved system performance of Fe loaded MgH<jats:sub>2<\/jats:sub> is attributed to restrictions on crystal growth of MgH<jats:sub>2<\/jats:sub> and the catalytic behavior of Fe nanoparticles, rather than any intrinsic catalytic properties offered by the formed mixed metal phase Mg<jats:sub>2<\/jats:sub>FeH<jats:sub>6<\/jats:sub>.<\/jats:p>","DOI":"10.1002\/cphc.201601078","type":"journal-article","created":{"date-parts":[[2016,11,17]],"date-time":"2016-11-17T12:26:43Z","timestamp":1479385603000},"page":"287-291","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":22,"title":["Dehydrogenation Properties of Magnesium Hydride Loaded with Fe, Fe\u2212C, and Fe\u2212Mg Additives"],"prefix":"10.1002","volume":"18","author":[{"given":"D.","family":"Pukazhselvan","sequence":"first","affiliation":[{"name":"Nanoengineering Research Group Centre for Mechanical Technology and Automation (TEMA) Department of 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Ceramic Engineering University of Aveiro  3810-193 Aveiro Portugal"}]},{"given":"Duncan P.","family":"Fagg","sequence":"additional","affiliation":[{"name":"Nanoengineering Research Group Centre for Mechanical Technology and Automation (TEMA) Department of Mechanical Engineering University of Aveiro  3810-193 Aveiro 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