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The successful preparation of the composites was confirmed by Fourier\u2010Transform Infrared spectroscopy (FT\u2010IR), powder X\u2010ray diffraction (XRD), scanning electron microscope (SEM\/EDS), transmission electron microscopy (TEM), elemental analysis, and nitrogen adsorption\u2010desorption isotherms. The resulting Fe1@aptesSBA\u201015 and Fe2@aptesSBA\u201015 composites were tested as the first SBA\u201015\u2010based heterogeneous catalysts for the conversion of furfuryl alcohol under mild reaction conditions (80 to 100\u2009\u00b0C) and with an environmentally friendly oxidant (TBHP, 70\u2009% aq. sol. with 1\u2009:\u20091 oxidant\/substrate molar ratio). The influence of various factors, such as reaction time, amounts of oxidant and catalyst, was investigated. The reaction time can be fairly reduced by adopting a microwave\u2010assisted method allowing it to reach complete conversion after 0.25\u2005h, in the absence of any added solvent or additive. Under these conditions, a vigorous furfuryl alcohol polymerization process occurred, with furfural as a by\u2010product. Recycling studies were carried out for Fe2@aptesSBA\u201015 and after four consecutive runs, the overall conversion of furfuryl alcohol remained high (\u226599\u2009%), without an appreciable change in the obtained yield.<\/jats:p>","DOI":"10.1002\/cplu.202200363","type":"journal-article","created":{"date-parts":[[2022,12,15]],"date-time":"2022-12-15T07:58:45Z","timestamp":1671091125000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Iron(III) Arylhydrazone Complexes Immobilized on Amine\u2010Functionalized Mesoporous Silica: Catalysts for the Valorization of Biomass\u2010Derived Furfuryl Alcohol"],"prefix":"10.1002","volume":"88","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2636-2934","authenticated-orcid":false,"given":"Mohamed M. 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Conselheiro Em\u00eddio Navarro 1959-007 Lisboa Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0986-6607","authenticated-orcid":false,"given":"Carlos M.","family":"Granadeiro","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE Departamento de Qu\u00edmica e Bioqu\u00edmica Faculdade de Ci\u00eancias Universidade do Porto  Rua do Campo Alegre s\/n 4169-007 Porto Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8984-0473","authenticated-orcid":false,"given":"Salete S.","family":"Balula","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE Departamento de Qu\u00edmica e Bioqu\u00edmica Faculdade de Ci\u00eancias Universidade do Porto  Rua do Campo Alegre s\/n 4169-007 Porto Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8323-888X","authenticated-orcid":false,"given":"Armando J. 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