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Estimation of the metastable zone width for different isothermal crystallization conditions can be modeled according to a chosen reference set of growth experiments carried out in the volume diffusion regime at different initial supersaturations, using seed crystals of a certain characteristic size. Moreover, the activation free energy of the secondary nucleation was estimated. The role of the enthalpy of immersion in the formation of secondary nucleation events inside the metastable zone was pointed out, as well as its effect in causing extra\u2010fast growth rate. Furthermore, sucrose crystal surface free energy was estimated. (\u00a9 2011 WILEY\u2010VCH Verlag GmbH &amp; Co. KGaA, Weinheim)<\/jats:p>","DOI":"10.1002\/crat.201000509","type":"journal-article","created":{"date-parts":[[2011,3,4]],"date-time":"2011-03-04T09:55:55Z","timestamp":1299232555000},"page":"373-382","source":"Crossref","is-referenced-by-count":4,"title":["Metastable zone width for secondary nucleation and secondary nucleation inside the metastable zone"],"prefix":"10.1002","volume":"46","author":[{"given":"I.","family":"Khaddour","sequence":"first","affiliation":[]},{"given":"F.","family":"Rocha","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2011,3,4]]},"reference":[{"key":"e_1_2_1_2_2","doi-asserted-by":"crossref","unstructured":"A.Mersmann Crystallization Technology Handbook (Marcel Deckker Inc. New York 2001).","DOI":"10.1201\/9780203908280"},{"key":"e_1_2_1_3_2","doi-asserted-by":"crossref","unstructured":"J. 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