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This work describes the reductive depolymerization of several types of plastic waste into value\u2010added compounds, including 1,6\u2010hexanediol, 1,2\u2010propanediol, <jats:italic>p<\/jats:italic>\u2010xylene and tetrahydrofuran, in good yields using the eco\u2010friendly, air\u2010stable, commercially available and very cheap catalyst Zn(OAc)<jats:sub>2<\/jats:sub>\u2009\u22c5\u20092H<jats:sub>2<\/jats:sub>O. This is the first example of the reductive depolymerization of polyester waste catalyzed by a zinc catalyst. Moreover, the catalytic system silane\/Zn(OAc)<jats:sub>2<\/jats:sub>\u2009\u22c5\u20092H<jats:sub>2<\/jats:sub>O was successfully applied to the reduction of polycaprolactone (PCL) on the gram scale with good yield and also to the selective reductive depolymerization of plastic mixtures. Finally, this work demonstrated that the catalyst Zn(OAc)<jats:sub>2<\/jats:sub>\u2009\u22c5\u20092H<jats:sub>2<\/jats:sub>O can be used in at least 7 cycles with good yields.<\/jats:p>","DOI":"10.1002\/cssc.202100130","type":"journal-article","created":{"date-parts":[[2021,3,5]],"date-time":"2021-03-05T13:03:51Z","timestamp":1614949431000},"page":"4228-4233","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":66,"title":["Reductive Depolymerization of Plastic Waste Catalyzed by Zn(OAc)<sub>2<\/sub>\u2009\u22c5\u20092H<sub>2<\/sub>O"],"prefix":"10.1002","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5919-7723","authenticated-orcid":false,"given":"Ana C.","family":"Fernandes","sequence":"first","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural Instituto Superior T\u00e9cnico Universidade de Lisboa  Av. 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