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The two most promising eutectogels were further optimized by adding ethyl hexylacrylate (HA) to the eutectogel formulation to improve the compatibility between the eutectic solvent and polymer network and to enhance the water resistance of the resulting membranes. Thermal analysis confirmed the successful formation and integration of eutectic solvents within the polymer network. Rheological studies demonstrated the rubber\u2010like behavior of the prepared hydrophobic eutectogels, with menthol\u2010based variants exhibiting superior mechanical properties. Finally, sorption experiments were conducted using the optimized octanoic acid:menthol\u2002PEGDA\u2010HA eutectogel to evaluate its efficiency in removing various contaminants of emerging concern (CECs), including diclofenac, iopromide, cefazolin, bisphenol A, and dichlorophenol. The results revealed high sorption capacities for bisphenol A (3213\u2005mg\u22c5kg<jats:sup>\u22121<\/jats:sup>) and dichlorophenol (2981\u2005mg\u22c5kg<jats:sup>\u22121<\/jats:sup>), followed by diclofenac (1490\u2005mg\u22c5kg<jats:sup>\u22121<\/jats:sup>), whereas minimal sorption capacities were observed for iopromide and cefazolin. Overall, this study demonstrates the potential of hydrophobic eutectogels as efficient and tunable materials for water purification, paving the way for their application in the environmental remediation of different emerging pollutants related to global change and human activities.<\/jats:p>","DOI":"10.1002\/cssc.202500307","type":"journal-article","created":{"date-parts":[[2025,6,3]],"date-time":"2025-06-03T05:29:10Z","timestamp":1748928550000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Hydrophobic Eutectogels for the Removal of Contaminants of Emerging Concern from Water"],"prefix":"10.1002","volume":"18","author":[{"given":"Elena","family":"Gabirondo","sequence":"first","affiliation":[{"name":"CEMMPRE ARISE Department of Chemical Engineering University of Coimbra  Rua S\u00edlvio Lima Coimbra 3030-790 Portugal"},{"name":"LAQV REQUIMTE Department of Chemistry NOVA School of Science and Technology FCT NOVA Universidade NOVA de Lisboa  Caparica 2829-516 Portugal"},{"name":"POLYMAT and Department of Polymers and Advanced Materials: Physics Chemistry and Technology Faculty of Chemistry University of the Basque Country UPV\/EHU  P\u00b0Manuel de Lardizabal, 3 20018 Donostia-San Sebastian Spain"}]},{"given":"Joao M. 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