{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,3]],"date-time":"2026-04-03T15:29:53Z","timestamp":1775230193624,"version":"3.50.1"},"reference-count":24,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2003,8,14]],"date-time":"2003-08-14T00:00:00Z","timestamp":1060819200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Eur J Inorg Chem"],"published-print":{"date-parts":[[2003,10]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Lanthanide complexes of 2,6\u2010dihydroxybenzoic acid (2,6\u2010Hdhb), namely [<jats:italic>n<\/jats:italic>Bu<jats:sub>4<\/jats:sub>N]<jats:sub>2<\/jats:sub>[Ln(2,6\u2010dhb)<jats:sub>5<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)<jats:sub>2<\/jats:sub>] [Ln = Sm (<jats:bold>1<\/jats:bold>) and Tb (<jats:bold>2<\/jats:bold>)], were synthesized and their crystal structures determined by single\u2010crystal X\u2010ray diffraction studies. The 2,6\u2010dhb<jats:sup>\u2212<\/jats:sup> ligand coordinates to the lanthanide cations through the carboxylate group in a monodentate or bidentate chelating coordination mode. The compounds were further characterised using IR, Raman, <jats:sup>1<\/jats:sup>H and <jats:sup>13<\/jats:sup>C NMR spectroscopy and elemental analysis. Photoluminescence measurements were performed on both compounds. In particular, the terbium complex <jats:bold>2 <\/jats:bold>shows intense photoluminescence both in the solid state and in ethanolic solution. Compound <jats:bold>2<\/jats:bold> also exhibits triboluminescence. (\u00a9 Wiley\u2010VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2003)<\/jats:p>","DOI":"10.1002\/ejic.200300084","type":"journal-article","created":{"date-parts":[[2003,9,19]],"date-time":"2003-09-19T10:36:42Z","timestamp":1063967802000},"page":"3609-3617","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":36,"title":["Lanthanide Complexes of 2,6\u2010Dihydroxybenzoic Acid: Synthesis, Crystal Structures and Luminescent Properties of [<i>n<\/i>Bu<sub>4<\/sub>N]<sub>2<\/sub>[Ln(2,6\u2010dhb)<sub>5<\/sub>(H<sub>2<\/sub>O)<sub>2<\/sub>] (Ln = Sm and Tb)"],"prefix":"10.1002","volume":"2003","author":[{"given":"Paula\u00a0C.\u00a0R.","family":"Soares\u2010Santos","sequence":"first","affiliation":[]},{"given":"Helena\u00a0I.\u00a0S.","family":"Nogueira","sequence":"additional","affiliation":[]},{"given":"Filipe\u00a0A.","family":"Almeida Paz","sequence":"additional","affiliation":[]},{"given":"Rute\u00a0A.","family":"S\u00e1 Ferreira","sequence":"additional","affiliation":[]},{"given":"Lu\u00eds\u00a0D.","family":"Carlos","sequence":"additional","affiliation":[]},{"given":"Jacek","family":"Klinowski","sequence":"additional","affiliation":[]},{"given":"Tito","family":"Trindade","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2003,9,18]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1039\/a706522a"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(99)00054-5"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(99)00220-9"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199013041"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm021188j"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-1902(75)80695-6"},{"key":"e_1_2_6_7_2","first-page":"2087","volume":"72","author":"Brzyska W.","year":"1998","journal-title":"Pol. J. Chem."},{"key":"e_1_2_6_8_2","first-page":"2524","volume":"72","author":"Brzyska W.","year":"1998","journal-title":"Pol. J. Chem."},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1080\/00958979908023587"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/DT9950001775"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(99)00282-0"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(00)91262-3"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1524\/zkri.1988.184.3-4.275"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(00)85348-7"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0277-5387(99)00061-3"},{"key":"e_1_2_6_16_2","unstructured":"C. Oldham inComprehensive Coordination Chemistry 1st ed. (Ed.: S. G. Wilkinson) Pergamon Press Oxford 1987 vol. 2 p. 435\u2212459."},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-2313(01)00212-5"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1039\/a904411f"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00308a025"},{"key":"e_1_2_6_20_2","unstructured":"STOE Cie GmbH Win XPOW THEO Version 1.15 1999."},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889893002018"},{"key":"e_1_2_6_22_2","unstructured":"G. M. Sheldrick SHELXL 97 Program for Crystal Structure Refinement University of G\u00f6ttingen 1997."},{"key":"e_1_2_6_23_2","unstructured":"G. M. Sheldrick SHELXS 97 Program for Crystal Structure Solution University of G\u00f6ttingen 1997."},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767394005726"}],"container-title":["European Journal of Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fejic.200300084","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/ejic.200300084","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/ejic.200300084","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/ejic.200300084","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T19:37:21Z","timestamp":1760384241000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/ejic.200300084"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2003,9,18]]},"references-count":24,"journal-issue":{"issue":"19","published-print":{"date-parts":[[2003,10]]}},"alternative-id":["10.1002\/ejic.200300084"],"URL":"https:\/\/doi.org\/10.1002\/ejic.200300084","archive":["Portico"],"relation":{},"ISSN":["1434-1948","1099-0682"],"issn-type":[{"value":"1434-1948","type":"print"},{"value":"1099-0682","type":"electronic"}],"subject":[],"published":{"date-parts":[[2003,9,18]]},"assertion":[{"value":"2003-02-12","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2003-09-18","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}