{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,20]],"date-time":"2026-01-20T05:50:40Z","timestamp":1768888240579,"version":"3.49.0"},"reference-count":32,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2004,2,10]],"date-time":"2004-02-10T00:00:00Z","timestamp":1076371200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Eur J Inorg Chem"],"published-print":{"date-parts":[[2004,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A series of new M[(dcbdt)<jats:sub>2<\/jats:sub>]<jats:sup>\u2212<\/jats:sup><jats:sup><jats:italic>z<\/jats:italic><\/jats:sup> complexes of the dicyanobenzodithiolate (dcbdt) ligand with a range of transition metals (M\u00a0=\u00a0Co, Pd, Pt, Cu, Au and Zn) in different oxidation states (<jats:italic>z<\/jats:italic>\u00a0=\u00a00.4, 1, 2) were prepared as their <jats:italic>n<\/jats:italic>Bu<jats:sub>4<\/jats:sub>N salts and characterised by X\u2010ray diffraction, cyclic voltammetry, EPR and static magnetic susceptibility. Their properties are discussed in comparison with the Ni and Fe analogues described by us recently. The structures of these complexes belong to four distinct groups: i) the Zn<jats:sup>II<\/jats:sup> compound <jats:bold>10<\/jats:bold> is triclinic <jats:italic>P<\/jats:italic><jats:styled-content>$\\bar 1$<jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/tex2gif-ueqn-1.gif\" xlink:title=\"equation image\"\/><\/jats:styled-content>\n with the metal in a tetrahedral coordination geometry; ii) other M<jats:sup>II<\/jats:sup> complexes [M\u00a0=\u00a0Pt (<jats:bold>8<\/jats:bold>), Pd (<jats:bold>7<\/jats:bold>), Co (<jats:bold>3<\/jats:bold>) and Cu (<jats:bold>5<\/jats:bold>)] are monoclinic <jats:italic>C<\/jats:italic>2\/<jats:italic>m<\/jats:italic>, and are isostructural with the Ni<jats:sup>II<\/jats:sup> analogue, presenting a perfectly planar square geometry; iii) the Co<jats:sup>III<\/jats:sup> compound <jats:bold>4<\/jats:bold> is triclinic <jats:italic>P<\/jats:italic><jats:styled-content>$\\bar 1$<jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/tex2gif-ueqn-2.gif\" xlink:title=\"equation image\"\/><\/jats:styled-content>\n, and isostructural with the Fe and Ni analogues, with a strong dimerisation of the M(dcbdt)<jats:sub>2<\/jats:sub> units and the metal in a square\u2010pyramidal coordination geometry; iv) the M<jats:sup>III<\/jats:sup> salts with M\u00a0=\u00a0Au (<jats:bold>2<\/jats:bold>), Cu (<jats:bold>6<\/jats:bold>) and Pt (<jats:bold>9<\/jats:bold>) are monoclinic <jats:italic>P<\/jats:italic>2<jats:sub>1<\/jats:sub>\/<jats:italic>c<\/jats:italic> and the complexes are arranged as pseudo\u2010dimers. The EPR and static magnetic\u2010susceptibility measurements show that the Co<jats:sup>II<\/jats:sup> (<jats:bold>3<\/jats:bold>), Cu<jats:sup>II<\/jats:sup> (<jats:bold>5<\/jats:bold>), Pt<jats:sup>III<\/jats:sup> (<jats:bold>9<\/jats:bold>) and Co<jats:sup>III<\/jats:sup> (<jats:bold>4<\/jats:bold>) complexes are paramagnetic corresponding to an <jats:italic>S<\/jats:italic> = 1\/2 state, except for Co<jats:sup>III<\/jats:sup>, which is in a high\u2010spin <jats:italic>S<\/jats:italic>\u00a0=\u00a01 configuration. The solid state EPR spectra of the Co<jats:sup>II<\/jats:sup> compound presents a hyperfine structure typical of the <jats:italic>I<\/jats:italic>\u00a0=\u00a07\/2 <jats:sup>59<\/jats:sup>Co. The temperature dependence of the paramagnetic susceptibility of the Pt<jats:sup>III<\/jats:sup> compound follows a singlet\u2010triplet model with a dimer antiferromagnetic coupling, <jats:italic>J<\/jats:italic>, of 984\u00a0K. (\u00a9 Wiley\u2010VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2004) <\/jats:p>","DOI":"10.1002\/ejic.200300476","type":"journal-article","created":{"date-parts":[[2004,3,9]],"date-time":"2004-03-09T11:02:05Z","timestamp":1078830125000},"page":"1318-1329","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":55,"title":["A Series of Transition Metal Bis(dicyanobenzenedithiolate) Complexes [M(dcbdt)<sub>2<\/sub>] (M = Fe, Co, Ni, Pd, Pt, Cu, Au and Zn)"],"prefix":"10.1002","volume":"2004","author":[{"given":"Helena","family":"Alves","sequence":"first","affiliation":[]},{"given":"Dulce","family":"Sim\u00e3o","sequence":"additional","affiliation":[]},{"given":"Isabel","family":"Cordeiro Santos","sequence":"additional","affiliation":[]},{"given":"Vasco","family":"Gama","sequence":"additional","affiliation":[]},{"given":"Rui","family":"Teives Henriques","sequence":"additional","affiliation":[]},{"given":"Hor\u00e1cio","family":"Novais","sequence":"additional","affiliation":[]},{"given":"Manuel","family":"Almeida","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2004,3,8]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(01)00457-X"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-1-4684-4175-8_6"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/0010-8545(91)80024-8"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/0010-8545(60)80003-3"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470166123.ch4"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470166116.ch2"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00069a027"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00032a008"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0682(200112)2001:12<3119::AID-EJIC3119>3.0.CO;2-0"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0379-6779(00)00980-2"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0379-6779(02)00411-3"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0277-5387(03)00211-0"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja00973a021"},{"key":"e_1_2_6_14_2","unstructured":"H. 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