{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,25]],"date-time":"2026-04-25T07:21:10Z","timestamp":1777101670085,"version":"3.51.4"},"reference-count":40,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2005,6,1]],"date-time":"2005-06-01T00:00:00Z","timestamp":1117584000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Eur J Inorg Chem"],"published-print":{"date-parts":[[2005,6]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The synthesis, structure, and physical properties of the oxalate\u2010based molecular magnets with the formula [Z<jats:sup>II<\/jats:sup>(bpy)<jats:sub>3<\/jats:sub>][ClO<jats:sub>4<\/jats:sub>][M<jats:sup>II<\/jats:sup>Fe<jats:sup>III<\/jats:sup>(ox)<jats:sub>3<\/jats:sub>] (Z<jats:sup>II<\/jats:sup> = Fe, Ru; M<jats:sup>II<\/jats:sup> = Mn, Fe; bpy = 2,2'\u2010bipyridine; ox = oxalate dianion) are presented here. All compounds are isostructural and crystallize in the chiral cubic space group <jats:italic>P<\/jats:italic>4<jats:sub>1<\/jats:sub>32, and contain three\u2010dimensional dimetallic networks formed by alternating M<jats:sup>II<\/jats:sup> and M<jats:sup>III<\/jats:sup> ions that are connected by oxalate anions. These compounds exhibit strong antiferromagnetic interactions that give rise to magnetic ordering as ferrimagnets or weak ferromagnets, with critical temperatures of up to 20 K, which is twice as high as those found for the isostructural magnets based on Cr<jats:sup>III<\/jats:sup>, as determined by magnetic measurements and M\u00f6ssbauer spectroscopy. (\u00a9 Wiley\u2010VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2005)<\/jats:p>","DOI":"10.1002\/ejic.200400977","type":"journal-article","created":{"date-parts":[[2005,6,1]],"date-time":"2005-06-01T09:17:58Z","timestamp":1117617478000},"page":"2064-2070","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":45,"title":["Oxalate\u2010Based 3D Chiral Magnets: The Series [Z<sup>II<\/sup>(bpy)<sub>3<\/sub>][ClO<sub>4<\/sub>][M<sup>II<\/sup>Fe<sup>III<\/sup>(ox)<sub>3<\/sub>] (Z<sup>II<\/sup> = Fe, Ru; M<sup>II<\/sup> = Mn, Fe; bpy = 2,2'\u2010Bipyridine; ox = Oxalate Dianion)"],"prefix":"10.1002","volume":"2005","author":[{"given":"Eugenio","family":"Coronado","sequence":"first","affiliation":[]},{"given":"Jos\u00e9 R.","family":"Gal\u00e1n\u2010Mascar\u00f3s","sequence":"additional","affiliation":[]},{"given":"Carlos J.","family":"G\u00f3mez\u2010Garc\u00eda","sequence":"additional","affiliation":[]},{"given":"Eugenia","family":"Mart\u00ednez\u2010Ferrero","sequence":"additional","affiliation":[]},{"given":"Manuel","family":"Almeida","sequence":"additional","affiliation":[]},{"given":"Jo\u00e3o C.","family":"Waerenborgh","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2005,6]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470166468.ch4"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1039\/a803165g"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm980321y"},{"key":"e_1_2_6_4_2","unstructured":"\u00a0"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(03)00119-X"},{"key":"e_1_2_6_6_2","first-page":"430","author":"Batten S. 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