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The N,O\u2010ligands in <jats:bold>4<\/jats:bold> and <jats:bold>5<\/jats:bold> result from fragmentation of the <jats:italic>N<\/jats:italic>\u2010hydroxyiminodicarboxylic acids. All the complexes have been characterized by IR, <jats:sup>1<\/jats:sup>H and <jats:sup>13<\/jats:sup>C NMR spectroscopy, FAB<jats:sup>+<\/jats:sup>\u2010MS, elemental analysis and X\u2010ray diffraction structural analysis, which indicate a \u03c0\u2010delocalized chelated benzoylhydrazidorhenium ring in <jats:bold>1<\/jats:bold> and <jats:bold>2<\/jats:bold>, and, in the other complexes, an essentially linear \u03b7<jats:sup>1<\/jats:sup>\u2010diazenido ligand that is always <jats:italic>trans<\/jats:italic> to the O\u2010coordinated carboxylate moiety of the N,O\u2010ligand. The complexes act as catalysts (TON values up to about 45) for peroxidative oxidation, by radical mechanisms, of cyclohexane and cyclopentane to the corresponding alcohols and ketones, under mild conditions (room temperature, use of aqueous H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> and without added acid). This is an unprecedented use of inorganic Re coordination compounds as catalysts in alkane functionalization. (\u00a9 Wiley\u2010VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2005)<\/jats:p>","DOI":"10.1002\/ejic.200400991","type":"journal-article","created":{"date-parts":[[2005,6,1]],"date-time":"2005-06-01T09:18:06Z","timestamp":1117617486000},"page":"2071-2080","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":47,"title":["Preparation and Crystal Structures of Benzoylhydrazido\u2010 and\u2010diazenidorhenium Complexes with N,O\u2010Ligands and Their Catalytic Activity Towards Peroxidative Oxidation of Cycloalkanes"],"prefix":"10.1002","volume":"2005","author":[{"given":"Alexander M.","family":"Kirillov","sequence":"first","affiliation":[]},{"given":"Matti","family":"Haukka","sequence":"additional","affiliation":[]},{"given":"M. F\u00e1tima C.","family":"Guedes da Silva","sequence":"additional","affiliation":[]},{"given":"Armando J. 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