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The electrochemical, spectroscopic and solvatochromic properties of these compounds were studied. These results suggest that efficient \u03c0\u2010conjugated systems are obtained due to the low\u2010energy charge\u2010transfer between the metal atom and the heterocyclic moieties. (\u00a9 Wiley\u2010VCH Verlag GmbH &amp; Co. 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