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The results are consistent with the formation of a 2:1 (host\u2010to\u2010guest) inclusion complex. Ab initio calculations were carried out in order to investigate the possible inclusion geometries. The best host\u2013guest fit was obtained for a tilted geometry of the ferrocene fragment relative to the \u03b2\u2010CD axis ( = 29\u00b0) with a 140\u2010pm inclusion of the corresponding Fe centre below the plane of the rim. The structure of the organometallic trimer allows its inclusion interaction with a second \u03b2\u2010CD host, leading to the 2:1 stoichiometry. (\u00a9 Wiley\u2010VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2005)<\/jats:p>","DOI":"10.1002\/ejic.200500551","type":"journal-article","created":{"date-parts":[[2005,10,25]],"date-time":"2005-10-25T04:22:51Z","timestamp":1130214171000},"page":"4729-4734","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Experimental and Theoretical Study of the Encapsulation of a Linear Oligo(ferrocenylsilane) Trimer with \u03b2\u2010Cyclodextrin"],"prefix":"10.1002","volume":"2005","author":[{"given":"Jos\u00e9 A.","family":"Fernandes","sequence":"first","affiliation":[]},{"given":"S\u00e9rgio","family":"Lima","sequence":"additional","affiliation":[]},{"given":"Susana S.","family":"Braga","sequence":"additional","affiliation":[]},{"given":"Martyn","family":"Pillinger","sequence":"additional","affiliation":[]},{"given":"Jos\u00e9 E.","family":"Rodr\u00edguez\u2010Borges","sequence":"additional","affiliation":[]},{"given":"Paulo","family":"Ribeiro\u2010Claro","sequence":"additional","affiliation":[]},{"given":"Jos\u00e9 J. 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