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Complexes <jats:bold>2<\/jats:bold>\u2013<jats:bold>6<\/jats:bold> were characterized by IR spectroscopy, <jats:sup>1<\/jats:sup>H\u2010, <jats:sup>31<\/jats:sup>P{<jats:sup>1<\/jats:sup>H}\u2010 and <jats:sup>13<\/jats:sup>C{<jats:sup>1<\/jats:sup>H} NMR spectroscopy, FAB\u2010MS, cyclic voltammetry, elemental analyses and single\u2010crystal X\u2010ray diffraction (for <jats:bold>2<\/jats:bold>, <jats:bold>5<\/jats:bold> and <jats:bold>6<\/jats:bold>) analyses which indicate mutually <jats:italic>trans<\/jats:italic> triphenylphosphane ligands. The redox behaviour of the obtained complexes in solution was studied, and the Lever electrochemical ligand parameter <jats:italic>E<\/jats:italic><jats:sub>L<\/jats:sub> was determined, for the first time, for 4,7\u2010Ph<jats:sub>2<\/jats:sub>\u2010phen. Compounds <jats:bold>2<\/jats:bold>\u2013<jats:bold>6<\/jats:bold> represent the first examples of <jats:italic>mono<\/jats:italic>\u2010 and <jats:italic>dicarbonyl<\/jats:italic> Re complexes bearing these types of ligands.(\u00a9 Wiley\u2010VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2007)<\/jats:p>","DOI":"10.1002\/ejic.200601026","type":"journal-article","created":{"date-parts":[[2007,3,2]],"date-time":"2007-03-02T08:42:17Z","timestamp":1172824937000},"page":"1556-1565","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Synthesis, Characterization and Redox Behaviour of Mono\u2010 and Dicarbonyl Phosphane Rhenium(I) Complexes Bearing N\u2010, N,N\u2010 and N,O\u2010Type Ligands"],"prefix":"10.1002","volume":"2007","author":[{"given":"Alexander M.","family":"Kirillov","sequence":"first","affiliation":[]},{"given":"Matti","family":"Haukka","sequence":"additional","affiliation":[]},{"given":"M. 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