{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,10]],"date-time":"2025-12-10T15:21:02Z","timestamp":1765380062392,"version":"build-2065373602"},"reference-count":29,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2008,1,7]],"date-time":"2008-01-07T00:00:00Z","timestamp":1199664000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Eur J Inorg Chem"],"published-print":{"date-parts":[[2008,3]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Molybdenum(II) complexes [MoX(CO)<jats:sub>2<\/jats:sub>(\u03b7<jats:sup>3<\/jats:sup>\u2010allyl)(CH<jats:sub>3<\/jats:sub>CN)<jats:sub>2<\/jats:sub>] (X = Cl or Br) were encapsulated in an aluminium\u2010pillared natural clay or a porous clay heterostructure and allowed to react with bidentate diimine ligands. All the materials obtained were characterised by several solid\u2010state techniques. Powder XRD, and <jats:sup>27<\/jats:sup>Al and <jats:sup>29<\/jats:sup>Si MAS NMR were used to investigate the integrity of the pillared clay during the modification treatments. <jats:sup>13<\/jats:sup>C CP MAS NMR, FTIR, elemental analyses and low\u2010temperature nitrogen adsorption showed that the immobilisation of the precursor complexes was successful as well as the in situ ligand\u2010substitution reaction. The new complex [MoBr(CO)<jats:sub>2<\/jats:sub>(\u03b7<jats:sup>3<\/jats:sup>\u2010allyl)(2\u2010aminodipyridyl)] was characterised by single\u2010crystal X\u2010ray diffraction and spectroscopic techniques, and NMR studies were used to investigate its fluxional behaviour in solution. The prepared materials are active for the oxidation of <jats:italic>cis<\/jats:italic>\u2010cyclooctene using <jats:italic>tert<\/jats:italic>\u2010butyl hydroperoxide as oxidant, though the activity of the isolated complexes is higher. (\u00a9 Wiley\u2010VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2008)<\/jats:p>","DOI":"10.1002\/ejic.200700939","type":"journal-article","created":{"date-parts":[[2008,1,7]],"date-time":"2008-01-07T09:10:54Z","timestamp":1199697054000},"page":"1147-1156","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Immobilisation of \u03b7<sup>3<\/sup>\u2010Allyldicarbonyl Complexes of Mo<sup>II<\/sup> with Bidentate Nitrogen Ligands within Aluminium\u2010Pillared Clays"],"prefix":"10.1002","volume":"2008","author":[{"given":"Jo\u00e3o Carlos","family":"Alonso","sequence":"first","affiliation":[]},{"given":"Patr\u00edcia","family":"Neves","sequence":"additional","affiliation":[]},{"given":"Carlos","family":"Silva","sequence":"additional","affiliation":[]},{"given":"Anabela A.","family":"Valente","sequence":"additional","affiliation":[]},{"given":"Paula","family":"Brand\u00e3o","sequence":"additional","affiliation":[]},{"given":"Susana","family":"Quintal","sequence":"additional","affiliation":[]},{"given":"Maria J.","family":"Villa de Brito","sequence":"additional","affiliation":[]},{"given":"Patr\u00edcia","family":"Pinto","sequence":"additional","affiliation":[]},{"given":"V\u00edtor","family":"F\u00e9lix","sequence":"additional","affiliation":[]},{"given":"M. G. B.","family":"Drew","sequence":"additional","affiliation":[]},{"given":"Jo\u00e3o","family":"Pires","sequence":"additional","affiliation":[]},{"given":"Ana Paula","family":"Carvalho","sequence":"additional","affiliation":[]},{"given":"Maria Jos\u00e9","family":"Calhorda","sequence":"additional","affiliation":[]},{"given":"Paula","family":"Ferreira","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2008,2,19]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1016\/0927-6513(95)00089-5"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1081\/CR-100100261"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/374529a0"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/cm011559g"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/b307226f"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200400521"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1039\/B401830C"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2005.12.023"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/om700348w"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(00)81713-2"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(01)00988-3"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2003.08.004"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50093a023"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20020402)8:7<1649::AID-CHEM1649>3.0.CO;2-U"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.micromeso.2004.05.009"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2006.05.007"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-004-3760-y"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0682(200010)2000:10<2263::AID-EJIC2263>3.0.CO;2-U"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2004.10.004"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200400852"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20020517)8:10<2370::AID-CHEM2370>3.0.CO;2-A"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200304887"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200300278"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00213a014"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)87677-9"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889888007903"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767383000252"},{"key":"e_1_2_6_28_2","unstructured":"G. M. Sheldrick SHELX\u201097 University of G\u00f6ttingen G\u00f6ttingen 1997."},{"key":"e_1_2_6_29_2","unstructured":"A. L. Spek PLATON A Multipurpose Crystallographic Tool Utrecht University Utrecht The Netherlands 1999."}],"container-title":["European Journal of Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fejic.200700939","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/ejic.200700939","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/ejic.200700939","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/ejic.200700939","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T22:01:20Z","timestamp":1760392880000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/ejic.200700939"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2008,2,19]]},"references-count":29,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2008,3]]}},"alternative-id":["10.1002\/ejic.200700939"],"URL":"https:\/\/doi.org\/10.1002\/ejic.200700939","archive":["Portico"],"relation":{},"ISSN":["1434-1948","1099-0682"],"issn-type":[{"type":"print","value":"1434-1948"},{"type":"electronic","value":"1099-0682"}],"subject":[],"published":{"date-parts":[[2008,2,19]]},"assertion":[{"value":"2007-09-07","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2008-02-19","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}