{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,6]],"date-time":"2025-11-06T19:49:40Z","timestamp":1762458580953,"version":"build-2065373602"},"reference-count":26,"publisher":"Wiley","issue":"6","license":[{"start":{"date-parts":[[2007,12,3]],"date-time":"2007-12-03T00:00:00Z","timestamp":1196640000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Eur J Inorg Chem"],"published-print":{"date-parts":[[2008,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Since the discovery of ferromagnetism well above room temperature in the Co\u2010doped TiO<jats:sub>2<\/jats:sub> system, diluted magnetic semiconductors based on TiO<jats:sub>2<\/jats:sub> doped with transition metals have generated great interest because of their potential use in the development of spintronic devices. The purpose of this paper is to report on a new and swift chemical route to synthesise highly stable anatase single\u2010phase Co\u2010 and Fe\u2010doped TiO<jats:sub>2<\/jats:sub> nanoparticles, with dopant concentrations of up to 10 at.\u2010% and grain sizes that range between 20 and 30 nm. Complementary structural, microstructural and chemical analyses of the different nanopowders synthesised strongly support the hypothesis that a homogeneous distribution of the dopant element in the substitutional sites of the anatase structure has been achieved. Moreover, UV\/Vis diffuse reflectance spectra of powder samples show redshifts to lower energies and decreasing bandgap energies with increasing Co or Fe concentration, which is consistent with n\u2010type doping of the TiO<jats:sub>2<\/jats:sub> anatase matrix. Films of Co\u2010doped TiO<jats:sub>2<\/jats:sub> were successfully deposited onto Si (100) substrates by the dip\u2010coating method, with suspensions of Ti<jats:sub>1\u2013<jats:italic>x<\/jats:italic><\/jats:sub>Co<jats:italic><jats:sub>x<\/jats:sub><\/jats:italic>O<jats:sub>2<\/jats:sub> nanoparticles in ethylene glycol.(\u00a9 Wiley\u2010VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2008)<\/jats:p>","DOI":"10.1002\/ejic.200700978","type":"journal-article","created":{"date-parts":[[2007,12,3]],"date-time":"2007-12-03T10:21:21Z","timestamp":1196677281000},"page":"961-965","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":38,"title":["A New Chemical Route to Synthesise TM\u2010Doped (TM = Co, Fe) TiO<sub>2<\/sub> Nanoparticles"],"prefix":"10.1002","volume":"2008","author":[{"given":"Manuel R.","family":"Nunes","sequence":"first","affiliation":[]},{"given":"Olinda C.","family":"Monteiro","sequence":"additional","affiliation":[]},{"given":"Ana L.","family":"Castro","sequence":"additional","affiliation":[]},{"given":"Duarte A.","family":"Vasconcelos","sequence":"additional","affiliation":[]},{"given":"Ant\u00f3nio J.","family":"Silvestre","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2008,2,12]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0167-5729(02)00100-0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1088\/0953-8984\/17\/27\/R01"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevB.67.115211"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0169-4332(03)00898-5"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jmmm.2007.02.081"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1088\/0953-8984\/18\/27\/L01"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.1056186"},{"key":"e_1_2_6_8_2","volume":"40","author":"Matsumoto Y.","year":"2001","journal-title":"Jpn. 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