{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,15]],"date-time":"2025-12-15T13:52:33Z","timestamp":1765806753857,"version":"build-2065373602"},"reference-count":103,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2009,1,13]],"date-time":"2009-01-13T00:00:00Z","timestamp":1231804800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Eur J Inorg Chem"],"published-print":{"date-parts":[[2009,2]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The reactions of Cu<jats:sup>II<\/jats:sup> carboxylates (valerate, 2\u2010methylbutyrate, hexanoate, heptanoate) with pyrazole (Hpz) in EtOH or EtOH\/water solutions easily afford the triangular trinuclear copper derivatives [Cu<jats:sub>3<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>\u2010OH)(\u03bc\u2010pz)<jats:sub>3<\/jats:sub>(RCOO)<jats:sub>2<\/jats:sub>(L)<jats:italic><jats:sub>x<\/jats:sub><\/jats:italic>] [R = CH<jats:sub>3<\/jats:sub>(CH<jats:sub>2<\/jats:sub>)<jats:sub>3<\/jats:sub>, L = H<jats:sub>2<\/jats:sub>O, <jats:italic>x<\/jats:italic> = 1 for <jats:bold>5<\/jats:bold>; R = CH<jats:sub>3<\/jats:sub>CH<jats:sub>2<\/jats:sub>CH(CH<jats:sub>3<\/jats:sub>), L = EtOH, <jats:italic>x<\/jats:italic> = 2 for <jats:bold>6<\/jats:bold>; R = CH<jats:sub>3<\/jats:sub>(CH<jats:sub>2<\/jats:sub>)<jats:sub>4<\/jats:sub>, L = EtOH, <jats:italic>x<\/jats:italic> = 1 for <jats:bold>7<\/jats:bold>; R = CH<jats:sub>3<\/jats:sub>(CH<jats:sub>2<\/jats:sub>)<jats:sub>5<\/jats:sub>, L = EtOH, <jats:italic>x<\/jats:italic> = 1 for <jats:bold>8<\/jats:bold>] as it has been previously found for R = H, L = Hpz, <jats:italic>x<\/jats:italic> = 2, (<jats:bold>1<\/jats:bold>); R = CH<jats:sub>3<\/jats:sub>, L = Hpz, <jats:italic>x<\/jats:italic> = 1, (<jats:bold>2<\/jats:bold>); R = CH<jats:sub>3<\/jats:sub>CH<jats:sub>2<\/jats:sub>, L = EtOH, <jats:italic>x<\/jats:italic> = 1, (<jats:bold>3<\/jats:bold>) and [Cu<jats:sub>3<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>\u2010OH)(\u03bc\u2010pz)<jats:sub>3<\/jats:sub>(CH<jats:sub>3<\/jats:sub>(CH<jats:sub>2<\/jats:sub>)<jats:sub>2<\/jats:sub>COO)<jats:sub>2<\/jats:sub>(MeOH)(H<jats:sub>2<\/jats:sub>O)], (<jats:bold>4<\/jats:bold>). The trinuclear structure common to <jats:bold>5<\/jats:bold>\u2013<jats:bold>8<\/jats:bold> has been assigned on the basis of magnetic susceptibility studies, ESI MS, IR and UV\/Vis spectroscopy as well as <jats:sup>1<\/jats:sup>H NMR measurements. The room temp. magnetic susceptibilities of <jats:bold>5<\/jats:bold>\u2013<jats:bold>8<\/jats:bold> almost correspond to the presence of a single unpaired electron for each trinuclear unit. The IR spectra exhibit signals due to the bridging \u03bc<jats:sub>3<\/jats:sub>\u2010OH in accordance with what was observed in the spectra of <jats:bold>1<\/jats:bold>\u2013<jats:bold>4<\/jats:bold>. Solid\u2010state and MeOH solution UV\/Vis spectra show the same features previously reported for <jats:bold>1<\/jats:bold>\u2013<jats:bold>4<\/jats:bold> and <jats:sup>1<\/jats:sup>H NMR spectra of <jats:bold>1<\/jats:bold>\u2013<jats:bold>8<\/jats:bold> show almost identical low field signals that can be assigned to pz<jats:sup>\u2013<\/jats:sup> hydrogens. A detailed investigation of the supramolecular structures of <jats:bold>1<\/jats:bold> and <jats:bold>4<\/jats:bold> and the single\u2010crystal X\u2010ray study of the polymeric <jats:italic>paddlewheel<\/jats:italic> Cu(2\u2010methylbutyrate)<jats:sub>2<\/jats:sub>, <jats:bold>A<\/jats:bold>, are also reported. Electrochemical experiments show that in <jats:bold>1<\/jats:bold>\u2013<jats:bold>8<\/jats:bold> the Cu<jats:sup>II<\/jats:sup> ions can be reduced, in distinct steps, to Cu<jats:sup>I<\/jats:sup> and Cu<jats:sup>0<\/jats:sup>. All the complexes act as catalysts or catalyst precursors for the efficient peroxidative oxidation, by aqueous hydrogen peroxide in acetonitrile and at room temp., of cycloalkanes RH (cyclohexane and cyclopentane) to the corresponding cyclic alcohols and ketones, with overall yields of up to 34\u2009% and TONs up to 42. Radical pathways involving the formation of alkyl hydroperoxides (ROOH) are involved.(\u00a9 Wiley\u2010VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2009)<\/jats:p>","DOI":"10.1002\/ejic.200800842","type":"journal-article","created":{"date-parts":[[2009,1,13]],"date-time":"2009-01-13T08:29:19Z","timestamp":1231835359000},"page":"666-676","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":83,"title":["Trinuclear Triangular Copper(II) Clusters \u2013 Synthesis, Electrochemical Studies and Catalytic Peroxidative Oxidation of Cycloalkanes"],"prefix":"10.1002","volume":"2009","author":[{"given":"Corrado","family":"Di Nicola","sequence":"first","affiliation":[]},{"given":"Federica","family":"Garau","sequence":"additional","affiliation":[]},{"given":"Yauhen Y.","family":"Karabach","sequence":"additional","affiliation":[]},{"given":"Lu\u00edsa M. D. R. S.","family":"Martins","sequence":"additional","affiliation":[]},{"given":"Magda","family":"Monari","sequence":"additional","affiliation":[]},{"given":"Luciano","family":"Pandolfo","sequence":"additional","affiliation":[]},{"given":"Claudio","family":"Pettinari","sequence":"additional","affiliation":[]},{"given":"Armando J. L.","family":"Pombeiro","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2009,1,29]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"\u00a0"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/9780470166475.ch3"},{"volume-title":"Advances in Inorganic and Bioinorganic Mechanisms","year":"1983","author":"Fenton D. E.","key":"e_1_2_6_3_2"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00012a020"},{"key":"e_1_2_6_5_2","unstructured":"D. Gatteschi O. Kahn J. S. Miller F. Palacio); NATO ASI Series 198; Kluwer Academic Publishers 1991 Dordrecht The Netherlands"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1039\/DT9930001349"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00104a010"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr950046o"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.199600431"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr9500390"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/0010-8545(95)01172-2"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0009-2614(96)01424-8"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/b007094g"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr950047g"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1126\/science.273.5283.1848"},{"key":"e_1_2_6_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja971049g"},{"volume-title":"The Biological Chemistry of the Elements","year":"2001","key":"e_1_2_6_17_2"},{"key":"e_1_2_6_18_2","unstructured":"S. Itoh in Comprehensive Coordination Chemistry J. A. McCleverty T. J. Meyer L. Que W. B. Tolman) 2003 Elsevier Dordrecht"},{"key":"e_1_2_6_19_2","unstructured":"D. H. Lee in Comprehensive Coordination Chemistry J. A. McCleverty T. J. Meyer L. Que W. B. Tolman) 2003 Elsevier Dordrecht"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2004.05.046"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1080\/10409230490475507"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature03311"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic0507870"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198908481"},{"key":"e_1_2_6_25_2","unstructured":"\u00a0"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200500585"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.200505216"},{"key":"e_1_2_6_28_2","unstructured":"\u00a0"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic049260y"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic050678l"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic061595n"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1080\/00958970500266206"},{"key":"e_1_2_6_33_2","unstructured":"H\u2010bonds concerning data and figures reported in the Supporting Information have been obtained by using the CIF files supplied as Supporting Information in refs. 5b (compounds1and4) and 5a (compound2). To these CIF files are also referred the atom labels used here."},{"key":"e_1_2_6_34_2","unstructured":"The Cambridge Structural Database contains 667 crystal structures where the [Cu2(RCOO)4]paddlewheelmoiety is present but only 19 of them refer to polymeric unsubstituted copper(II) carboxylates."},{"key":"e_1_2_6_35_2","unstructured":"Crystal data for C20H36Cu2O4 A: triclinic space groupP$\\bar {1}$(No. 2) a= 5.1829(6) b= 11.1982(13) c= 11.8865(14) \u00c5 \u03b1= 65.631(2)\u00b0 \u03b2= 88.023(2)\u00b0 \u03b3= 88.948(2) V= 628.04(13) \u00c53 Z= 1 R(Rw) [I> 2\u03c3(I)] = 0.0448 (0.1388). The X\u2010ray intensity data forAwere recorded on a Bruker SMART Apex II CCD area detector diffractometer [\u03bb= 0.71073 \u00c5 T= 293(2) K)]. Cell dimensions and the orientation matrix were initially determined from a least\u2010squares refinement on reflections measured in three sets of 20 exposures collected in three different\u03c9regions and eventually refined against all data. For all crystals a full sphere of reciprocal space was scanned in 0.3\u00b0\u03c9steps. The software SMART[10]was used for collecting frames of data indexing reflections and determining lattice parameters. The collected frames were then processed for integration by the SAINT program[10]and an empirical absorption correction was applied using SADABS.[11]The structure was solved by direct methods (SIR 97)[12]and subsequent Fourier syntheses and refined by full\u2010matrix least\u2010squares onF2(SHELXTL)[13]using anisotropic thermal parameters for all non\u2010hydrogen atoms. Some disorder in the carboxylate chains was detected and in particular in one of the chains there was a disorder between the methyl and ethyl chains bound at C(3) and a second position for the methyl [bound to C(9) and alternative to C(10)]. Therefore the site occupation factors of the methyls were refined yielding 0.54 for C(10) 0.26 for C(81) and 0.19 for C(91) respectively. All hydrogen atoms were added in calculated positions included in the final stage of refinement with isotropic thermal parameters U(H) = 1.2Ueq(C) [U(H) = 1.5Ueq(C\u2013Me)] and allowed to ride on their carrier carbons. Molecular graphics were generated using Mercury[14]and Schakal[15]software. CCDC\u2010697289 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre viawww.ccdc.cam.ac.uk\/data_request\/cif."},{"key":"e_1_2_6_36_2","unstructured":"SMART & SAINT Software Reference Manuals version 5.051 (Windows NT Version) Bruker Analytical X\u2010ray Instruments Inc. Madison WI 1998."},{"key":"e_1_2_6_37_2","unstructured":"G. M. Sheldrick SADABS program for empirical absorption correction University of G\u00f6ttingen Germany 1996."},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889898007717"},{"key":"e_1_2_6_39_2","unstructured":"G. M. Sheldrick SHELXTLplus (Windows NT Version) Structure Determination Package Version 5.1 Bruker Analytical X\u2010ray Instruments Inc. Madison WI USA 1998."},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1107\/S002188980600731X"},{"key":"e_1_2_6_41_2","unstructured":"E. Keller SCHAKAL A Computer Program for the Graphic Representation of Molecular and Crystallographic Models Institute for Crystallography of the University of Freiburg Freiburg (Germany) 1997."},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)80455-5"},{"key":"e_1_2_6_43_2","doi-asserted-by":"crossref","unstructured":"E. Pretsch T. Clerc J. Seibl W. Simon Tables of Determination of Organic Compounds.13C NMR 1H NMR IR MS UV\/Vis Chemical Laboratory Practice Springer\u2010Verlag Berlin Germany 1989.","DOI":"10.1007\/978-3-662-10207-7_1"},{"key":"e_1_2_6_44_2","unstructured":"\u00a0"},{"key":"e_1_2_6_45_2","doi-asserted-by":"crossref","first-page":"1181","DOI":"10.1002\/recl.19630821207","volume":"82","author":"Van der Kerk G. J. M.","year":"1963","journal-title":"Recl. Trav. Chem. Pays\u2010Bas"},{"key":"e_1_2_6_46_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(00)93860-X"},{"key":"e_1_2_6_47_2","doi-asserted-by":"publisher","DOI":"10.1002\/recl.19730920903"},{"key":"e_1_2_6_48_2","unstructured":"\u00a0"},{"key":"e_1_2_6_49_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2004.05.022"},{"key":"e_1_2_6_50_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic010670l"},{"key":"e_1_2_6_51_2","unstructured":"It is well known that in ESI MS conditions aggregation phenomena leading to oligomeric species may occur. See as an example"},{"key":"e_1_2_6_52_2","doi-asserted-by":"publisher","DOI":"10.1038\/367720a0"},{"key":"e_1_2_6_53_2","doi-asserted-by":"publisher","DOI":"10.1002\/mas.1280140203"},{"key":"e_1_2_6_54_2","doi-asserted-by":"publisher","DOI":"10.1021\/ed073pA118"},{"key":"e_1_2_6_55_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0020-1693(99)00151-6"},{"key":"e_1_2_6_56_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic020375g"},{"key":"e_1_2_6_57_2","unstructured":"M. W. Senko IsoPro Isotopic Abundance Simulator v. 2.1 National High Magnetic Field Laboratory Los Alamos National Laboratory Los Alamos NM 1994."},{"key":"e_1_2_6_58_2","doi-asserted-by":"publisher","DOI":"10.1021\/cg060501h"},{"key":"e_1_2_6_59_2","unstructured":"C. Di Nicola F. Garau M. Monari L. Pandolfo C. Pettinari Proceedings of VIII Congresso Nazionale di Chimica Supramolecolare Trieste (Italy) Sept. 19\u201322 2007 P53."},{"key":"e_1_2_6_60_2","unstructured":"\u00a0"},{"key":"e_1_2_6_61_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2007.02.025"},{"key":"e_1_2_6_62_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja072531u"},{"key":"e_1_2_6_63_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200700980"},{"key":"e_1_2_6_64_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200400991"},{"key":"e_1_2_6_65_2","doi-asserted-by":"publisher","DOI":"10.1021\/cg060310e"},{"key":"e_1_2_6_66_2","doi-asserted-by":"publisher","DOI":"10.1002\/adsc.200700529"},{"key":"e_1_2_6_67_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2006.09.038"},{"key":"e_1_2_6_68_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200800355"},{"key":"e_1_2_6_69_2","unstructured":"\u00a0"},{"key":"e_1_2_6_70_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2005.05.035"},{"key":"e_1_2_6_71_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2006.02.041"},{"key":"e_1_2_6_72_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2006.09.049"},{"key":"e_1_2_6_73_2","unstructured":"G. S. Mishra E. C. B. Alegria L. R. Martins J. J. R. Fra\u00fasto da Silva A. J. L. Pombeiro J. Mol. Cat. A: Chem.in press."},{"key":"e_1_2_6_74_2","doi-asserted-by":"publisher","DOI":"10.1039\/b005513l"},{"key":"e_1_2_6_75_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2004.08.048"},{"key":"e_1_2_6_76_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jinorgbio.2007.11.007"},{"key":"e_1_2_6_77_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1381-1169(03)00420-5"},{"key":"e_1_2_6_78_2","doi-asserted-by":"publisher","DOI":"10.1039\/b608790f"},{"key":"e_1_2_6_79_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tetlet.2003.10.016"},{"key":"e_1_2_6_80_2","doi-asserted-by":"publisher","DOI":"10.1039\/b306382h"},{"key":"e_1_2_6_81_2","doi-asserted-by":"publisher","DOI":"10.1023\/A:1019054415786"},{"key":"e_1_2_6_82_2","unstructured":"\u00a0"},{"key":"e_1_2_6_83_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1381-1169(02)00196-6"},{"key":"e_1_2_6_84_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1631-0748(03)00021-3"},{"key":"e_1_2_6_85_2","unstructured":"\u00a0"},{"key":"e_1_2_6_86_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr020628n"},{"key":"e_1_2_6_87_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(00)00320-9"},{"key":"e_1_2_6_88_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20000616)6:12<2152::AID-CHEM2152>3.0.CO;2-O"},{"key":"e_1_2_6_89_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja964068j"},{"key":"e_1_2_6_90_2","unstructured":"\u00a0"},{"key":"e_1_2_6_91_2","doi-asserted-by":"publisher","DOI":"10.1002\/9783527619405"},{"volume-title":"Organic Reactions Catalyzed by Metal Complexes","year":"1988","author":"Shul'pin G. B.","key":"e_1_2_6_92_2"},{"key":"e_1_2_6_93_2","unstructured":"\u00a0"},{"key":"e_1_2_6_94_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(02)01182-1"},{"key":"e_1_2_6_95_2","doi-asserted-by":"publisher","DOI":"10.1039\/b101442k"},{"key":"e_1_2_6_96_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0926-860X(01)00590-7"},{"key":"e_1_2_6_97_2","doi-asserted-by":"publisher","DOI":"10.1039\/P29950001459"},{"key":"e_1_2_6_98_2","doi-asserted-by":"publisher","DOI":"10.1039\/CC9960001737"},{"key":"e_1_2_6_99_2","doi-asserted-by":"publisher","DOI":"10.1021\/jo00223a036"},{"key":"e_1_2_6_100_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2004.05.020"},{"key":"e_1_2_6_101_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200390219"},{"key":"e_1_2_6_102_2","doi-asserted-by":"publisher","DOI":"10.1039\/JR9570002545"},{"key":"e_1_2_6_103_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(01)00299-5"}],"container-title":["European Journal of Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fejic.200800842","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/ejic.200800842","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/ejic.200800842","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/ejic.200800842","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T11:04:11Z","timestamp":1760353451000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/ejic.200800842"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2009,1,29]]},"references-count":103,"journal-issue":{"issue":"5","published-print":{"date-parts":[[2009,2]]}},"alternative-id":["10.1002\/ejic.200800842"],"URL":"https:\/\/doi.org\/10.1002\/ejic.200800842","archive":["Portico"],"relation":{},"ISSN":["1434-1948","1099-0682"],"issn-type":[{"type":"print","value":"1434-1948"},{"type":"electronic","value":"1099-0682"}],"subject":[],"published":{"date-parts":[[2009,1,29]]},"assertion":[{"value":"2008-08-21","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2009-01-29","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}