{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,26]],"date-time":"2026-03-26T17:31:32Z","timestamp":1774546292703,"version":"3.50.1"},"reference-count":75,"publisher":"Wiley","issue":"36","license":[{"start":{"date-parts":[[2009,11,18]],"date-time":"2009-11-18T00:00:00Z","timestamp":1258502400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"Fundamental Research Fund of Ukraine","award":["Project 28.3\/017"],"award-info":[{"award-number":["Project 28.3\/017"]}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Eur J Inorg Chem"],"published-print":{"date-parts":[[2009,12]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Heterotrimetallic complex [Cu<jats:sup>II<\/jats:sup><jats:sub>2<\/jats:sub>Co<jats:sup>II<\/jats:sup>Ni<jats:sup>II<\/jats:sup><jats:sub>2<\/jats:sub>(Me<jats:sub>2<\/jats:sub>Ea)<jats:sub>5<\/jats:sub>Cl<jats:sub>5<\/jats:sub>(H<jats:sub>2<\/jats:sub>O)]<jats:bold>\u00b7<\/jats:bold>CH<jats:sub>3<\/jats:sub>CN<jats:bold>\u00b7<\/jats:bold>H<jats:sub>2<\/jats:sub>O has been prepared in a one\u2010pot reaction of zero\u2010valent copper with cobalt and nickel chlorides in an acetonitrile solution of 2\u2010(dimethylamino)ethanol (HMe<jats:sub>2<\/jats:sub>Ea) in the open air. The metal stoichiometry obtained by atomic absorption analysis was further confirmed by single\u2010crystal X\u2010ray diffraction investigations. The pentanuclear molecule is formed by a previously unknown combination of incomplete cube M<jats:sub>3<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>\u2010X)(\u03bc\u2010X)<jats:sub>3<\/jats:sub> and triangle bipyramidal M<jats:sub>3<\/jats:sub>(\u03bc<jats:sub>3<\/jats:sub>\u2010X)<jats:sub>2<\/jats:sub>(\u03bc\u2010X)<jats:sub>2<\/jats:sub> fragments, resulting in a zigzag arrangement of metal centers within one molecule. This type of arrangement is very uncommon for pentanuclear complexes and in particular for complexes with an odd number of metal centers. A search of the Cambridge Structural Database showed that the number of coordination compounds possessing an even number of metals is significantly greater than those containing an odd number. Possible reasons for such a distribution, as well as the synthetic and structural features of the presented compound, are discussed.(\u00a9 Wiley\u2010VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2009)<\/jats:p>","DOI":"10.1002\/ejic.200900815","type":"journal-article","created":{"date-parts":[[2009,11,18]],"date-time":"2009-11-18T14:24:37Z","timestamp":1258554277000},"page":"5469-5473","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":26,"title":["A Pentanuclear Cu\/Co\/Ni Complex with 2\u2010(Dimethylamino)ethanol \u2013 Observation of a Rare Molecular Structure Type and Its Place in General Structural Types: An Analysis of the Cambridge Structural Database"],"prefix":"10.1002","volume":"2009","author":[{"given":"Dmytro S.","family":"Nesterov","sequence":"first","affiliation":[]},{"given":"Vladimir N.","family":"Kokozay","sequence":"additional","affiliation":[]},{"given":"Brian W.","family":"Skelton","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2009,12,8]]},"reference":[{"key":"e_1_2_6_1_2","unstructured":"See for example:"},{"key":"e_1_2_6_2_2","volume-title":"Single\u2010Molecule Magnets and Related Phenomena","year":"2006"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0010-8545(02)00101-7"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200801608"},{"key":"e_1_2_6_5_2","unstructured":"\u00a0"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2006.03.021"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2005.05.013"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja066434x"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2004.12.019"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200504406"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3773(20020402)41:7<1114::AID-ANIE1114>3.0.CO;2-6"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcat.2003.10.028"},{"key":"e_1_2_6_13_2","unstructured":"S. K. Mandal H. W. Roesky Acc. Chem. Res.2009 ACS ASAP."},{"key":"e_1_2_6_14_2","unstructured":"\u00a0"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/b608790f"},{"key":"e_1_2_6_16_2","unstructured":"A. J. L.Pombeiro A. M.Kirillov M. N.Kopylovich V. N.Kokozay D. S.Nesterov PatentPT 103526 2007."},{"key":"e_1_2_6_17_2","unstructured":"\u00a0"},{"key":"e_1_2_6_18_2","volume-title":"Compr. Coord. Chem. II","author":"McCleverty J. A.","year":"2004"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1039\/b510102f"},{"key":"e_1_2_6_20_2","unstructured":"\u00a0"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1039\/b209168m"},{"key":"e_1_2_6_22_2","doi-asserted-by":"publisher","DOI":"10.1039\/b518461d"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0483443"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200503040"},{"key":"e_1_2_6_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr990110s"},{"key":"e_1_2_6_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1521-3765(19990903)5:9<2455::AID-CHEM2455>3.0.CO;2-H"},{"key":"e_1_2_6_27_2","doi-asserted-by":"publisher","DOI":"10.1039\/c39950002563"},{"key":"e_1_2_6_28_2","unstructured":"\u00a0"},{"key":"e_1_2_6_29_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2006.12.002"},{"key":"e_1_2_6_30_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2006.09.088"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1007\/s10971-008-1767-3"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1039\/b801351a"},{"key":"e_1_2_6_33_2","unstructured":"\u00a0"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1039\/b713252b"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2009.02.041"},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200390185"},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/1099-0682(200208)2002:8<2163::AID-EJIC2163>3.0.CO;2-4"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1039\/b009194o"},{"key":"e_1_2_6_39_2","doi-asserted-by":"publisher","DOI":"10.1039\/b509810f"},{"key":"e_1_2_6_40_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic049044p"},{"key":"e_1_2_6_41_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2008.10.037"},{"key":"e_1_2_6_42_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2008.07.013"},{"key":"e_1_2_6_43_2","unstructured":"\u00a0"},{"key":"e_1_2_6_44_2","doi-asserted-by":"publisher","DOI":"10.1039\/B612788F"},{"key":"e_1_2_6_45_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic048955w"},{"key":"e_1_2_6_46_2","volume":"62","author":"Nesterov D. S.","year":"2006","journal-title":"Acta Crystallogr., Sect. C"},{"key":"e_1_2_6_47_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2005.07.032"},{"key":"e_1_2_6_48_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108768102003890"},{"key":"e_1_2_6_49_2","doi-asserted-by":"publisher","DOI":"10.1039\/a908426f"},{"key":"e_1_2_6_50_2","volume-title":"Infrared and Raman Spectra of Inorganic and Coordination Compounds","author":"Nakamoto K.","year":"1986"},{"key":"e_1_2_6_51_2","volume-title":"Structural Inorganic Chemistry","author":"Wells A. F.","year":"1983"},{"key":"e_1_2_6_52_2","unstructured":"\u00a0"},{"key":"e_1_2_6_53_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50194a038"},{"key":"e_1_2_6_54_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic9711630"},{"key":"e_1_2_6_55_2","doi-asserted-by":"publisher","DOI":"10.1039\/B418598F"},{"key":"e_1_2_6_56_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic800946v"},{"key":"e_1_2_6_57_2","unstructured":"\u00a0"},{"key":"e_1_2_6_58_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic0623157"},{"key":"e_1_2_6_59_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja050451p"},{"key":"e_1_2_6_60_2","unstructured":"\u00a0"},{"key":"e_1_2_6_61_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0277-5387(01)00754-9"},{"key":"e_1_2_6_62_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00028a005"},{"key":"e_1_2_6_63_2","doi-asserted-by":"publisher","DOI":"10.1039\/b809265f"},{"key":"e_1_2_6_64_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2008.03.007"},{"key":"e_1_2_6_65_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic50192a005"},{"key":"e_1_2_6_66_2","unstructured":"\u00a0"},{"key":"e_1_2_6_67_2","volume":"62","author":"Tahir A. A.","year":"2006","journal-title":"Acta Crystallogr., Sect. E"},{"key":"e_1_2_6_68_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200300708"},{"key":"e_1_2_6_69_2","doi-asserted-by":"publisher","DOI":"10.1039\/b103288g"},{"key":"e_1_2_6_70_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1387-7003(98)00042-2"},{"key":"e_1_2_6_71_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0277-5387(96)00454-8"},{"key":"e_1_2_6_72_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0471929"},{"key":"e_1_2_6_73_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr00104a003"},{"key":"e_1_2_6_74_2","unstructured":"SADABS Siemens X\u2010ray Instruments: Madison WI 1995."},{"key":"e_1_2_6_75_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767307043930"}],"container-title":["European Journal of Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fejic.200900815","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/ejic.200900815","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/ejic.200900815","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/ejic.200900815","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T13:25:56Z","timestamp":1760361956000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/ejic.200900815"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2009,12]]},"references-count":75,"journal-issue":{"issue":"36","published-print":{"date-parts":[[2009,12]]}},"alternative-id":["10.1002\/ejic.200900815"],"URL":"https:\/\/doi.org\/10.1002\/ejic.200900815","archive":["Portico"],"relation":{},"ISSN":["1434-1948","1099-0682"],"issn-type":[{"value":"1434-1948","type":"print"},{"value":"1099-0682","type":"electronic"}],"subject":[],"published":{"date-parts":[[2009,12]]},"assertion":[{"value":"2009-08-19","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2009-12-08","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}