{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T01:08:13Z","timestamp":1760404093151,"version":"build-2065373602"},"reference-count":38,"publisher":"Wiley","issue":"13","license":[{"start":{"date-parts":[[2013,3,21]],"date-time":"2013-03-21T00:00:00Z","timestamp":1363824000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Eur J Inorg Chem"],"published-print":{"date-parts":[[2013,5]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The initial employment of cyanato groups in higher oxidation state manganese cluster chemistry, in conjunction with the gem\u2010diolate form of di\u20102\u2010pyridylketone or 2,6\u2010diacetylpyridine dioxime chelate ligands, has afforded structurally interesting Mn<jats:sup>II\/III<\/jats:sup><jats:sub>14<\/jats:sub> and Mn<jats:sup>II\/III\/IV<\/jats:sup><jats:sub>16<\/jats:sub> clusters, respectively. In both complexes, the end\u2010on bridging cyanato groups show an obvious preference in binding through their O atom, a significantly different ligation than that for the homoatomic\u2010type N<jats:sub>3<\/jats:sub><jats:sup>\u2013<\/jats:sup> ligand. The Mn<jats:sub>14<\/jats:sub> compound shows entirely visible out\u2010of\u2010phase signals below 5 K and large hysteresis loops below 2 K.<\/jats:p>","DOI":"10.1002\/ejic.201300099","type":"journal-article","created":{"date-parts":[[2013,3,28]],"date-time":"2013-03-28T06:11:40Z","timestamp":1364451100000},"page":"2286-2290","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":18,"title":["Approaches to Molecular Magnetic Materials from the Use of Cyanate Groups in Higher Oxidation State Metal Cluster Chemistry: Mn<sub>14<\/sub> and Mn<sub>16<\/sub>"],"prefix":"10.1002","volume":"2013","author":[{"given":"Dimitris I.","family":"Alexandropoulos","sequence":"first","affiliation":[]},{"given":"Constantina","family":"Papatriantafyllopoulou","sequence":"additional","affiliation":[]},{"given":"Chaoran","family":"Li","sequence":"additional","affiliation":[]},{"given":"Lu\u00eds","family":"Cunha\u2010Silva","sequence":"additional","affiliation":[]},{"given":"Manolis J.","family":"Manos","sequence":"additional","affiliation":[]},{"given":"Anastasios J.","family":"Tasiopoulos","sequence":"additional","affiliation":[]},{"given":"Wolfgang","family":"Wernsdorfer","sequence":"additional","affiliation":[]},{"given":"George","family":"Christou","sequence":"additional","affiliation":[]},{"given":"Theocharis C.","family":"Stamatatos","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2013,3,21]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200390067"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1038\/ncomms1415"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature11341"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1039\/C1CS15115K"},{"key":"e_1_2_6_5_2","unstructured":"\u00a0"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic801217j"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200600552"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200501881"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200601467"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic801795x"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0316824"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/B708122G"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200353147"},{"key":"e_1_2_6_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3757(20010302)113:5<908::AID-ANGE908>3.0.CO;2-4"},{"key":"e_1_2_6_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/b106472j"},{"key":"e_1_2_6_16_2","unstructured":"\u00a0"},{"key":"e_1_2_6_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja960970f"},{"key":"e_1_2_6_18_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic902298y"},{"key":"e_1_2_6_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200801393"},{"key":"e_1_2_6_20_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic7020269"},{"key":"e_1_2_6_21_2","doi-asserted-by":"publisher","DOI":"10.1039\/C0CC01701A"},{"key":"e_1_2_6_22_2","unstructured":"\u00a0"},{"key":"e_1_2_6_23_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja106666h"},{"key":"e_1_2_6_24_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic801342f"},{"key":"e_1_2_6_25_2","unstructured":"\u00a0"},{"key":"e_1_2_6_26_2","unstructured":"Crystal structure data for1\u00b7xDMF\u00b7yH2O: C208H162Mn28N48O88 Mr= 6280.19 triclinic space groupP$\\bar {1}$ a= 16.1201(8) \u00c5 b= 20.8879(6) \u00c5 c= 22.0475(10) \u00c5 \u03b1= 85.219(3)\u00b0 \u03b2= 70.039(4)\u00b0 \u03b3= 82.447(3)\u00b0 V= 6911.3(5) \u00c53 Z= 1 \u03c1calcd.= 1.509 g\u2009cm\u20133 T= 100(2) K 86184 reflections collected 23965 unique (Rint= 0.1368) R1 = 0.0694 andwR2 = 0.1489 using 7224 reflections withI\u2009>\u20092\u03c3(I). The small size and weak diffraction of several mounted crystals did not allow us to determine the exact number of lattice solvate molecules a problem that is usually observed in many high\u2010nuclearity metal complexes.[13 15 16]Crystal structure data for2\u00b7x(solv): C88H98Mn16Cl2N32O40 Mr= 3193.92 monoclinic space groupP21\/c a= 14.5921(4) \u00c5 b= 21.4515(6) \u00c5 c= 23.1946(6) \u00c5 \u03b2= 100.600(2)\u00b0 V= 7136.5(3) \u00c53 Z= 2 \u03c1calcd.= 1.486 g\u2009cm\u20133 T= 150(2) K 101693 reflections collected 13532 unique (Rint= 0.0427) R1 = 0.0537 andwR2 = 0.1645 using 13532 reflections withI\u2009>\u20092\u03c3(I). The spaces created by the crystal packing of complexes contained considerable electron density mainly because of disordered lattice solvate molecules (most likely DMF). Several attempts to locate and model such molecules revealed to be unsuccessful as the electron density was highly smeared\u2010out thus avoiding full convergence upon full\u2010matrix least\u2010squares refinement cycles onF2. The searches for the total potential solvent area by using the software package PLATON[25a]revealed the existence of a large cavity with a potential solvent accessible void volume of ca. 1768 \u00c53. Subsequently the original data set was treated by using the SQUEEZE[25b]subroutines to fully remove the contribution of these highly disordered molecules in the solvent\u2010accessible volume (contribution of ca. 988 electrons was effectively removed). The calculated solvent\u2010free reflection list was then used for the final structure refinement;"},{"key":"e_1_2_6_27_2","unstructured":"CCDC\u2010905468 and CCDC\u2010905469 contain the supplementary crystallographic data for this paper. These data can be obtained free of charge from The Cambridge Crystallographic Data Centre viawww.ccdc.cam.ac.uk\/conts\/retrieving.html."},{"key":"e_1_2_6_28_2","doi-asserted-by":"publisher","DOI":"10.1039\/b001404o"},{"key":"e_1_2_6_29_2","unstructured":"See the Supporting Information."},{"key":"e_1_2_6_30_2","unstructured":"\u00a0"},{"key":"e_1_2_6_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ic00071a023"},{"key":"e_1_2_6_32_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108768185002063"},{"key":"e_1_2_6_33_2","doi-asserted-by":"publisher","DOI":"10.1039\/DT9840001349"},{"key":"e_1_2_6_34_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200501265"},{"key":"e_1_2_6_35_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja068961m"},{"key":"e_1_2_6_36_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja060796n"},{"key":"e_1_2_6_37_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889802022112"},{"key":"e_1_2_6_38_2","doi-asserted-by":"publisher","DOI":"10.1107\/S0108767389011189"}],"container-title":["European Journal of Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fejic.201300099","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/ejic.201300099","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/ejic.201300099","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/ejic.201300099","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T00:16:11Z","timestamp":1760400971000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/ejic.201300099"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2013,3,21]]},"references-count":38,"journal-issue":{"issue":"13","published-print":{"date-parts":[[2013,5]]}},"alternative-id":["10.1002\/ejic.201300099"],"URL":"https:\/\/doi.org\/10.1002\/ejic.201300099","archive":["Portico"],"relation":{},"ISSN":["1434-1948","1099-0682"],"issn-type":[{"type":"print","value":"1434-1948"},{"type":"electronic","value":"1099-0682"}],"subject":[],"published":{"date-parts":[[2013,3,21]]},"assertion":[{"value":"2013-01-23","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2013-03-21","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}