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The crystal structures of <jats:bold>1<\/jats:bold>\u2013<jats:bold>4<\/jats:bold> were determined by single\u2010crystal X\u2010ray diffraction, which revealed that the cyano groups from dithiolene complexes fail to coordinate the metal ions in the cyclam units. Instead, they are coordinated by solvent molecules or by dithiolene S atoms and cyclam N\u2013H groups, which participate in hydrogen bonds to the nitrile and sulfur moieties in the anions.<\/jats:p>","DOI":"10.1002\/ejic.201300490","type":"journal-article","created":{"date-parts":[[2013,7,10]],"date-time":"2013-07-10T03:40:45Z","timestamp":1373427645000},"page":"4612-4618","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Heterodimetallic Structures Based on Cyano\u2010Substituted Bis(dithiolene) Complexes and Ni and Cu Cyclam Cations"],"prefix":"10.1002","volume":"2013","author":[{"given":"Ana C.","family":"Cerdeira","sequence":"first","affiliation":[]},{"given":"Dulce","family":"Belo","sequence":"additional","affiliation":[]},{"given":"Sandra","family":"Raba\u00e7a","sequence":"additional","affiliation":[]},{"given":"Laura C. 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