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The structure determined by X\u2010ray crystallography reveals that it has an interesting 8\u2010ring channel 3D structure having the Co<jats:sub>2<\/jats:sub>\u2010dimers as the secondary building unit. Topological analysis shows that it has 10\u2010c uninodal 3D net structure with the Schl\u00e4fli symbol 3<jats:sup>15<\/jats:sup>.4<jats:sup>22<\/jats:sup>.5<jats:sup>8<\/jats:sup>. The magnetic measurement reveals the tetrahedral coordinated Co<jats:sup>II<\/jats:sup> ion. The compound is highly active towards epoxidation in the presence of air and IBA (isobutyraldehyde). It catalyses almost all types of olefinic substrates with equal efficiency. The compound is highly stable thermally (370 \u00b0C) and under the reaction conditions as well. 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