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The aerial oxidation of <jats:bold>2<\/jats:bold> leads to the formation of the dinuclear oxomolybdenum(V) chloride [Mo<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>(DMF)<jats:sub>4<\/jats:sub>(\u03bc\u2010O)<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>] (<jats:bold>3<\/jats:bold>). The structures of <jats:bold>2<\/jats:bold> and <jats:bold>3\u00b7<\/jats:bold>DMF have been determined by single\u2010crystal X\u2010ray diffraction. Compounds <jats:bold>1<\/jats:bold> and <jats:bold>3<\/jats:bold> were examined as promoters of phosphoester bond hydrolysis in <jats:italic>para<\/jats:italic>\u2010nitrophenylphosphate (<jats:italic>p<\/jats:italic>NPP), which was used as a model substrate. The reactions were performed in aqueous solution at 55 \u00b0C and followed by <jats:sup>1<\/jats:sup>H NMR spectroscopy. For assays performed with 30\u2013100 mol\u2010% of <jats:bold>1<\/jats:bold> or <jats:bold>3<\/jats:bold> relative to <jats:italic>p<\/jats:italic>NPP, both compounds promote the production of <jats:italic>para<\/jats:italic>\u2010nitrophenol (<jats:italic>p<\/jats:italic>NPh) from <jats:italic>p<\/jats:italic>NPP. Compound <jats:bold>3<\/jats:bold> is especially active in promoting the hydrolytic cleavage of the phosphoester bond (<jats:italic>t<\/jats:italic><jats:sub>1\/2<\/jats:sub>\u2009&lt; 80 min).<\/jats:p>","DOI":"10.1002\/ejic.201402071","type":"journal-article","created":{"date-parts":[[2014,7,7]],"date-time":"2014-07-07T05:47:06Z","timestamp":1404712026000},"page":"3681-3689","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Use of Organomolybdenum Compounds for Promoted Hydrolysis of Phosphoester Bonds in Aqueous Media"],"prefix":"10.1002","volume":"2014","author":[{"given":"Ana C.","family":"Gomes","sequence":"first","affiliation":[]},{"given":"Carla A.","family":"Gamelas","sequence":"additional","affiliation":[]},{"given":"Jos\u00e9 A.","family":"Fernandes","sequence":"additional","affiliation":[]},{"given":"Filipe A.","family":"Almeida Paz","sequence":"additional","affiliation":[]},{"given":"Patrique","family":"Nunes","sequence":"additional","affiliation":[]},{"given":"Martyn","family":"Pillinger","sequence":"additional","affiliation":[]},{"given":"Isabel S.","family":"Gon\u00e7alves","sequence":"additional","affiliation":[]},{"given":"Carlos C.","family":"Rom\u00e3o","sequence":"additional","affiliation":[]},{"given":"Marta","family":"Abrantes","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2014,7,7]]},"reference":[{"key":"e_1_2_6_1_2","first-page":"199","volume":"2","author":"Kumar S. 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