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The influence of the alkyl chain length on the structure of the BSs, represented by the notation C<jats:italic>n<\/jats:italic>\/siloxane (where <jats:italic>n<\/jats:italic> = 6 and 20), was examined. The C20\/siloxane hybrid is a hydrophobic material that exhibits a hierarchically structured lamellar bilayer organization, a texture composed of microplates of nanometer thickness, and a reversible time\u2010independent order\/disorder phase transition (onset at 60 \u00b0C). The driving forces for self\u2010assembly are van der Waals interactions between the icosanyl chains and \u03c0\u2010\u03c0 interactions between the triazole rings. In the essentially amorphous C6\/siloxane hybrid, the latter contribution promotes the genesis of a pre\u2010lamellar phase similar to that found in C20\/siloxane.<\/jats:p>","DOI":"10.1002\/ejic.201402673","type":"journal-article","created":{"date-parts":[[2014,10,1]],"date-time":"2014-10-01T13:42:30Z","timestamp":1412170950000},"page":"1218-1225","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Nanostructuring of Bridged Organosilane Precursors with Pendant Alkyl Chains"],"prefix":"10.1002","volume":"2015","author":[{"given":"S\u00edlvia C.","family":"Nunes","sequence":"first","affiliation":[]},{"given":"Krist\u00fdna","family":"B\u00fcrglov\u00e1","sequence":"additional","affiliation":[]},{"given":"Jana","family":"Hoda\u010dov\u00e1","sequence":"additional","affiliation":[]},{"given":"Rute A. 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