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The resultant composite materials were characterized by elemental analysis, powder X\u2010ray diffraction, FTIR spectroscopy, and <jats:sup>31<\/jats:sup>P magic\u2010angle spinning (MAS) NMR spectroscopy. The desulfurization of a model diesel containing three refractory organosulfur compounds (1\u2010benzothiophene, dibenzothiophene, and 4,6\u2010dimethyldibenzothiophene) was studied with the ionic liquid 1\u2010butyl\u20103\u2010methylimidazolium hexafluorophosphate as an extractant, the PW<jats:sub>11<\/jats:sub>Zn@MOF composites as sulfoxidation catalysts, and aqueous H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> as an oxidant. The composite obtained by direct synthesis was the most efficient catalyst and led to almost complete desulfurization of the model diesel under mild conditions. Moreover, the solid catalyst could be recovered readily and recycled without significant loss of desulfurization performance. The application of this system to the treatment of a real diesel sample provided a very good sulfur removal of 83\u2009% when combined with liquid\u2013liquid extraction.<\/jats:p>","DOI":"10.1002\/ejic.201600442","type":"journal-article","created":{"date-parts":[[2016,10,13]],"date-time":"2016-10-13T11:06:45Z","timestamp":1476356805000},"page":"5114-5122","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":49,"title":["Zinc\u2010Substituted Polyoxotungstate@amino\u2010MIL\u2010101(Al) \u2013 An Efficient Catalyst for the Sustainable Desulfurization of Model and Real Diesels"],"prefix":"10.1002","volume":"2016","author":[{"given":"Diana","family":"Juli\u00e3o","sequence":"first","affiliation":[{"name":"REQUIMTE\u2010LAQV Department of Chemistry and Biochemistry Faculty of Sciences University of Porto  4169\u2010007 Porto Portugal"},{"name":"Department of Chemistry CICECO \u2010 Aveiro Institute of Materials, University of Aveiro  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