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MOFs <jats:bold>1<\/jats:bold> and <jats:bold>3<\/jats:bold> have zigzag\u2010 and linear\u2010type 1D structures, respectively, whereas <jats:bold>2<\/jats:bold> and <jats:bold>4<\/jats:bold> possess rectangular grid\u2010 and layer\u2010type 2D structures. In <jats:bold>2<\/jats:bold> and in <jats:bold>4<\/jats:bold>, a dinuclear Zn<jats:sup>II<\/jats:sup> cluster (C<jats:sub>2<\/jats:sub>O<jats:sub>4<\/jats:sub>Zn<jats:sub>2<\/jats:sub>) and a trinuclear \u00b5<jats:sup>3<\/jats:sup>\u2010hydroxo\u2010bridged Cu<jats:sup>II<\/jats:sup> cluster [Cu<jats:sub>3<\/jats:sub>(OH)<jats:sub>2<\/jats:sub>]<jats:italic><jats:sub>n<\/jats:sub><\/jats:italic>, respectively, act as building block units. These frameworks act as heterogeneous catalysts (the Zn\u2010MOFs are more active than Cu\u2010MOFs, and <jats:bold>1<\/jats:bold> is the most efficient) for the cyanosilylation of aldehydes with trimethylsilyl cyanide at room temperature. These MOF\u2010based heterogeneous catalysts can be easily recovered and reused, at least over a few consecutive cycles, without losing activity.<\/jats:p>","DOI":"10.1002\/ejic.201600902","type":"journal-article","created":{"date-parts":[[2016,10,13]],"date-time":"2016-10-13T12:34:11Z","timestamp":1476362051000},"page":"5557-5567","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":35,"title":["Zinc(II) and Copper(II) Metal\u2013Organic Frameworks Constructed from a Terphenyl\u20104,4\u2032\u2032\u2010dicarboxylic Acid Derivative: Synthesis, Structure, and Catalytic Application in the Cyanosilylation of Aldehydes"],"prefix":"10.1002","volume":"2016","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3047-2204","authenticated-orcid":false,"given":"Anirban","family":"Karmakar","sequence":"first","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural Instituto Superior T\u00e9cnico Universidade de Lisboa Av. 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