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X\u2010ray diffraction, infrared spectroscopy and scanning electron microscopy indicated a successful intercalation of hexacyanoferrate in the sub\u2010micrometer sized platelet\u2010like particles. Release studies of hexacyanoferrate from LDHs found that the anion is released depending on the concentration of NaCl and under alkaline conditions. When placed in contact with carbon steel under corrosive conditions, the formation of Prussian blue was detected. Furthermore, the application of potentiodynamic polarization and electrochemical impedance spectroscopy revealed that hexacyanoferrate has a detrimental effect on the corrosion of carbon steel, while when intercalated in LDHs this effect is minimized. 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