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The flexibility of the organic linker posed a serious challenge in the preparation of crystalline materials: for this, the judicious selection of sulfuric acid to act as a mineralizing agent proved to be instrumental, acting in the retardation of the coordination of the phosphonic acid groups, as well as being an integral part the <jats:bold>UAV\u201015<\/jats:bold> by coordinating to the metal center. The material is a 3D network having channels filled with crystallization water molecules that can be easily removed by increasing of temperature (120\u2009\u00b0C for 24\u2005h), leading to a single\u2010crystal\u2010to\u2010single\u2010crystal transformation originating [La<jats:sub>2<\/jats:sub>(SO<jats:sub>4<\/jats:sub>)<jats:sub>2<\/jats:sub>(H<jats:sub>6<\/jats:sub>htp)(H<jats:sub>2<\/jats:sub>O)<jats:sub>3<\/jats:sub>] (<jats:bold>UAV\u201015\u2009d<\/jats:bold>). This transformation maintains the overall topology of <jats:bold>UAV\u201015<\/jats:bold> with only a small distortion of the framework. The reversibility of this transformation was studied, with the material reverting naturally to its original structure at ambient conditions for a period of 3\u2005months or, in a faster way, when immersed in water at 120\u2009\u00b0C for 24\u2005h.<\/jats:p>","DOI":"10.1002\/ejic.202400467","type":"journal-article","created":{"date-parts":[[2024,11,6]],"date-time":"2024-11-06T22:29:12Z","timestamp":1730932152000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Breathing Effect in a Tetrapodal Lanthanide\u2010Phosphonate Organic Framework"],"prefix":"10.1002","volume":"28","author":[{"given":"Ricardo F.","family":"Mendes","sequence":"first","affiliation":[{"name":"Department of Chemistry CICECO \u2013 Aveiro Institute of Materials University of Aveiro  3810-193 Aveiro Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2051-5645","authenticated-orcid":false,"given":"Filipe A.","family":"Almeida Paz","sequence":"additional","affiliation":[{"name":"Department of Chemistry CICECO \u2013 Aveiro Institute of Materials University of Aveiro  3810-193 Aveiro Portugal"}]}],"member":"311","published-online":{"date-parts":[[2024,12,13]]},"reference":[{"key":"e_1_2_8_1_1","doi-asserted-by":"publisher","DOI":"10.3390\/ma14020310"},{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2018.10.038"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr300014x"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CP06817H"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467-019-12754-w"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja202154j"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp303686m"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmaterialslett.9b00399"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.7b00162"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5TA10765B"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2016.09.037"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC01762K"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.4c00895"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2dt11992g"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889893002018"},{"key":"e_1_2_8_16_1","unstructured":"SAINT+ Data Integration Engine v. 8.37a\u00a91997\u20132015 Bruker AXS Madison Wisconsin USA."},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1107\/S1600576714022985"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053273314026370"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053229614024218"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889811043202"},{"key":"e_1_2_8_21_1","unstructured":"K. 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