{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,14]],"date-time":"2025-10-14T00:29:10Z","timestamp":1760401750674,"version":"build-2065373602"},"reference-count":71,"publisher":"Wiley","issue":"19","license":[{"start":{"date-parts":[[2025,6,11]],"date-time":"2025-06-11T00:00:00Z","timestamp":1749600000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["UIDB\/50011\/2020","UIDP\/50011\/2020 and LA\/P\/0006\/2020","2023.14213.PEX","2021.06403.BD","CEECIND\/02128\/2017","CEECIND\/00553\/2017","UIDB\/04326\/2020, UIDP\/04326\/2020 and LA\/P\/0101\/2020","EMBRC.PT ALG\u201001\u20100145\u2010FEDER\u2010022121"],"award-info":[{"award-number":["UIDB\/50011\/2020","UIDP\/50011\/2020 and LA\/P\/0006\/2020","2023.14213.PEX","2021.06403.BD","CEECIND\/02128\/2017","CEECIND\/00553\/2017","UIDB\/04326\/2020, UIDP\/04326\/2020 and LA\/P\/0101\/2020","EMBRC.PT ALG\u201001\u20100145\u2010FEDER\u2010022121"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["chemistry-europe.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Eur J Inorg Chem"],"published-print":{"date-parts":[[2025,7,12]]},"abstract":"<jats:p>The dinuclear oxoperoxomolybdenum(VI) complex [Mo<jats:sub>2<\/jats:sub>O<jats:sub>6<\/jats:sub>(OH)<jats:sub>2<\/jats:sub>(pto)<jats:sub>2<\/jats:sub>] (<jats:bold>1<\/jats:bold>), containing a rare example of a hydroxo\u2010bridged {MoO(O<jats:sub>2<\/jats:sub>)(<jats:italic>\u03bc<\/jats:italic>\u2010OH)<jats:sub>2<\/jats:sub>MoO(O<jats:sub>2<\/jats:sub>)}<jats:sup>0<\/jats:sup> core, has been synthesized via the reaction of MoO<jats:sub>3<\/jats:sub> with H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> and 5\u2010(2\u2010pyridyl\u20101\u2010oxide)tetrazole (Hpto) and characterized by elemental analysis and ICP\u2010OES, infrared and Raman spectroscopies, single crystal X\u2010ray diffraction, nuclear magnetic resonance, and mass spectrometry. Compound <jats:bold>1<\/jats:bold> is an effective homogeneous catalyst for olefin epoxidation. The type of oxidant, namely <jats:italic>tert<\/jats:italic>\u2010butyl hydroperoxide (TBHP) or H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub>, influences the catalytic performance. For <jats:italic>cis<\/jats:italic>\u2010cyclooctene epoxidation, <jats:bold>1<\/jats:bold>\/TBHP led to 100% conversion after 4\u2009h\u2009at 70\u2009\u00b0C, and <jats:bold>1<\/jats:bold>\/H<jats:sub>2<\/jats:sub>O<jats:sub>2<\/jats:sub> led to 80% conversion after 24\u2009h\u2009at 70\u2009\u00b0C. Catalyst recycling is feasible using an ionic liquid solvent with high affinity for the catalyst, and product separation via an extraction process. The catalytic potential of <jats:bold>1<\/jats:bold> was further explored for the chemical valorization of biomass\u2010derived fatty acid methyl esters (FAMEs), namely C18\u2010unsaturated methyl oleate and methyl linoleate derived from vegetable oils. The reaction of FAMEs\/TBHP gave mainly epoxidized FAMEs (&gt;97% selectivity at high conversions of 97\u2013100%, at 70\u2009\u00b0C). This catalyst is a rare example of a dinuclear organo\u2010oxomolybdenum(VI) compound with the ability to epoxidize FAMEs.<\/jats:p>","DOI":"10.1002\/ejic.202500090","type":"journal-article","created":{"date-parts":[[2025,6,12]],"date-time":"2025-06-12T01:19:37Z","timestamp":1749691177000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Dinuclear Oxoperoxomolybdenum(VI) Complex, [Mo<sub>2<\/sub>O<sub>6<\/sub>(OH)<sub>2<\/sub>(Pyridine Oxide Tetrazolate)<sub>2<\/sub>], Displaying the {MoO(O<sub>2<\/sub>)(<i>\u03bc<\/i>\u2010OH)<sub>2<\/sub>MoO(O<sub>2<\/sub>)}<sup>0<\/sup> Core, and its Catalytic Performance in Olefin Epoxidation"],"prefix":"10.1002","volume":"28","author":[{"given":"Martinique S.","family":"Nunes","sequence":"first","affiliation":[{"name":"CICECO \u2013 Aveiro Institute of Materials Department of Chemistry University of Aveiro Campus Universit\u00e1rio de Santiago  3810\u2010193 Aveiro Portugal"}]},{"given":"Patr\u00edcia","family":"Neves","sequence":"additional","affiliation":[{"name":"CICECO \u2013 Aveiro Institute of Materials Department of Chemistry University of Aveiro Campus Universit\u00e1rio de Santiago  3810\u2010193 Aveiro Portugal"}]},{"given":"Ana C.","family":"Gomes","sequence":"additional","affiliation":[{"name":"CICECO \u2013 Aveiro Institute of Materials Department of Chemistry University of Aveiro Campus Universit\u00e1rio de Santiago  3810\u2010193 Aveiro Portugal"}]},{"given":"Ricardo F.","family":"Mendes","sequence":"additional","affiliation":[{"name":"CICECO \u2013 Aveiro Institute of Materials Department of Chemistry University of Aveiro Campus Universit\u00e1rio de Santiago  3810\u2010193 Aveiro Portugal"}]},{"given":"Filipe A.","family":"Almeida Paz","sequence":"additional","affiliation":[{"name":"CICECO \u2013 Aveiro Institute of Materials Department of Chemistry University of Aveiro Campus Universit\u00e1rio de Santiago  3810\u2010193 Aveiro Portugal"}]},{"given":"Andr\u00e9 D.","family":"Lopes","sequence":"additional","affiliation":[{"name":"Centre of Marine Sciences (CCMAR\/CIMAR LA) Department of Chemistry and Pharmacy FCT University of the Algarve  8005\u2010039 Faro Portugal"}]},{"given":"Jos\u00e9 P.","family":"Da Silva","sequence":"additional","affiliation":[{"name":"Centre of Marine Sciences (CCMAR\/CIMAR LA) Department of Chemistry and Pharmacy FCT University of the Algarve  8005\u2010039 Faro Portugal"}]},{"given":"Martyn","family":"Pillinger","sequence":"additional","affiliation":[{"name":"CICECO \u2013 Aveiro Institute of Materials Department of Chemistry University of Aveiro Campus Universit\u00e1rio de Santiago  3810\u2010193 Aveiro Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3495-2133","authenticated-orcid":false,"given":"Anabela A.","family":"Valente","sequence":"additional","affiliation":[{"name":"CICECO \u2013 Aveiro Institute of Materials Department of Chemistry University of Aveiro Campus Universit\u00e1rio de Santiago  3810\u2010193 Aveiro Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2836-7715","authenticated-orcid":false,"given":"Isabel S.","family":"Gon\u00e7alves","sequence":"additional","affiliation":[{"name":"CICECO \u2013 Aveiro Institute of Materials Department of Chemistry University of Aveiro Campus Universit\u00e1rio de Santiago  3810\u2010193 Aveiro Portugal"}]}],"member":"311","published-online":{"date-parts":[[2025,6,11]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2007.05.002"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/C0DT00706D"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1134\/S1063774508010045"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1039\/c1dt10065c"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2012.09.019"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7DT03939E"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/b820629e"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1039\/DT9870000991"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2003.09.012"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molstruc.2008.01.001"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.poly.2013.02.027"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mcat.2017.01.016"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201800232"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules24010105"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.3390\/catal13030565"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1039\/b401919a"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.optmat.2012.02.039"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/bio.3075"},{"key":"e_1_2_8_20_1","first-page":"m213","volume":"67","author":"Gao F.","year":"2011","journal-title":"Acta Crystallogr. E Crystallogr. Commun."},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/om049107b"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201200068"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/qua.21595"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic701746r"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2012.02.038"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.inoche.2013.03.028"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1039\/c3nj00115f"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mcat.2017.09.036"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/C2DT31660A"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/a904440j"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.3390\/molecules24091814"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcata.2019.117154"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/dt9930002683"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CC04114J"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4DT01863J"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1007\/3-540-48664-X_4"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo9620324"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/b515484g"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-017-1991-y"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.2174\/138527212798993095"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/om9002522"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/1521-3765(20020517)8:10<2370::AID-CHEM2370>3.0.CO;2-A"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.200902873"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/chem.201000298"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.molcata.2004.04.002"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-016-1702-0"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1021\/ic102456z"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10562-009-9869-2"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200400331"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ica.2018.10.012"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/cctc.201100007"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.200900544"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2dt11751g"},{"key":"e_1_2_8_54_1","unstructured":"R.Sharma can be found underhttps:\/\/dataintelo.com\/report\/epoxy\u2010fatty\u2010acid\u2010methyl\u2010ester\u2010market 2024(accessed: February 2025)."},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.3390\/healthcare9050603"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3RA08684D"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.3390\/catal11070765"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/lipi.19950970707"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mcat.2023.113282"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11746-014-2560-9"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1007\/s11746-003-0792-z"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/ejic.201801096"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1002\/lipi.19930950608"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889893002018"},{"key":"e_1_2_8_65_1","unstructured":"APEX4 Data Collection Software Bruker AXS Inc. Delft The Netherlands 2021."},{"key":"e_1_2_8_66_1","unstructured":"SAINT + Data Integration Engine Version 8.37a Bruker AXS Inc. Madison WI USA 2015."},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1107\/S1600576714022985"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053273314026370"},{"key":"e_1_2_8_69_1","doi-asserted-by":"publisher","DOI":"10.1107\/S2053229614024218"},{"key":"e_1_2_8_70_1","doi-asserted-by":"publisher","DOI":"10.1107\/S0021889811043202"},{"volume-title":"Diamond\u2014Crystal and Molecular Structure Visualization","year":"2010","author":"Putz H.","key":"e_1_2_8_71_1"},{"key":"e_1_2_8_72_1","doi-asserted-by":"publisher","DOI":"10.1107\/S1600576719014092"}],"container-title":["European Journal of Inorganic Chemistry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/ejic.202500090","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T10:19:36Z","timestamp":1760350776000},"score":1,"resource":{"primary":{"URL":"https:\/\/chemistry-europe.onlinelibrary.wiley.com\/doi\/10.1002\/ejic.202500090"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,6,11]]},"references-count":71,"journal-issue":{"issue":"19","published-print":{"date-parts":[[2025,7,12]]}},"alternative-id":["10.1002\/ejic.202500090"],"URL":"https:\/\/doi.org\/10.1002\/ejic.202500090","archive":["Portico"],"relation":{},"ISSN":["1434-1948","1099-0682"],"issn-type":[{"type":"print","value":"1434-1948"},{"type":"electronic","value":"1099-0682"}],"subject":[],"published":{"date-parts":[[2025,6,11]]},"assertion":[{"value":"2025-01-29","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2025-06-11","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e202500090"}}