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The sense and degree of enantioselectivity attained is independent of both the leaving group and the isomeric structure of the initial allylic halide. DFT studies support the selective formation of a limited number of energetically favoured <jats:italic>anti<\/jats:italic> and <jats:italic>syn<\/jats:italic> \u03c0\u2010allyl intermediates. The observed regio\u2010 and enantioselectivity can be rationalised based on the energetics of these structures. (\u00a9 Wiley\u2010VCH Verlag GmbH &amp; Co. KGaA, 69451 Weinheim, Germany, 2009)<\/jats:p>","DOI":"10.1002\/ejoc.200801029","type":"journal-article","created":{"date-parts":[[2009,1,12]],"date-time":"2009-01-12T09:51:23Z","timestamp":1231753883000},"page":"898-903","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["Mapping the Mechanism of Nickel\u2010Ferrophite Catalysed Methylation of Baylis\u2013Hillman\u2010Derived S<sub>N<\/sub>2\u2032 Electrophiles"],"prefix":"10.1002","volume":"2009","author":[{"given":"Andrew","family":"Novak","sequence":"first","affiliation":[]},{"given":"Maria Jos\u00e9","family":"Calhorda","sequence":"additional","affiliation":[]},{"given":"Paulo Jorge","family":"Costa","sequence":"additional","affiliation":[]},{"given":"Simon","family":"Woodward","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2009,2,2]]},"reference":[{"key":"e_1_2_6_1_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.crci.2006.10.008"},{"key":"e_1_2_6_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/ejoc.200600071"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.tet.2004.12.002"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200463028"},{"key":"e_1_2_6_5_2","unstructured":"Review:"},{"key":"e_1_2_6_6_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.71.973"},{"key":"e_1_2_6_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/om000383"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/om060444p"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jorganchem.2006.02.023"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.196605821"},{"key":"e_1_2_6_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.196608971"},{"key":"e_1_2_6_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ol701584f"},{"key":"e_1_2_6_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)83562-7"},{"volume-title":"Density Functional Theory of Atoms and Molecules","year":"1989","author":"Parr R. 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