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This reactivity makes hypervalent iodine compounds highly attractive for the creation of electrophilic synthons of known nucleophiles, resulting in novel synthetic disconnections and the formation of new Nu(nucleophile)\u2212N bond.<\/jats:p><jats:p>Electrophilic sources of nitrogen\u2010based groups have been known for many decades and are of great synthetic importance. Traditionally, these reagents are limited to few examples. With the use of hypervalent iodine, the transfer of a wide diversity of nitrogen sources became a possibility. This review compiles the latest reported examples of hypervalent iodine reagents capable of electrophilic transfer of nitrogen\u2010based groups. It showcases the preparation of such reagents, their synthetic utility, and reaction mechanisms involving these group transfer reagents.<\/jats:p>","DOI":"10.1002\/ejoc.202300109","type":"journal-article","created":{"date-parts":[[2023,4,25]],"date-time":"2023-04-25T07:14:53Z","timestamp":1682406893000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":29,"title":["Reactivity of Hypervalent Iodine(III) Reagents Bearing Transferable <i>N<\/i>\u2010Based Groups"],"prefix":"10.1002","volume":"26","author":[{"given":"Jo\u00e3o","family":"Macara","sequence":"first","affiliation":[{"name":"LAQV-REQUIMTE Department of Chemistry NOVA School of Science and Technology Universidade Nova de Lisboa  2829-516 Caparica Portugal"}]},{"given":"Catarina","family":"Caldeira","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE Department of Chemistry NOVA School of Science and Technology Universidade Nova de Lisboa  2829-516 Caparica Portugal"}]},{"given":"Diogo L.","family":"Poeira","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE Department of Chemistry NOVA School of Science and Technology Universidade Nova de Lisboa  2829-516 Caparica Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6712-752X","authenticated-orcid":false,"given":"M. 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