{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,16]],"date-time":"2025-10-16T00:57:20Z","timestamp":1760576240756,"version":"build-2065373602"},"reference-count":14,"publisher":"Wiley","issue":"7","license":[{"start":{"date-parts":[[2006,3,8]],"date-time":"2006-03-08T00:00:00Z","timestamp":1141776000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["analyticalsciencejournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Electroanalysis"],"published-print":{"date-parts":[[2006,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>The interaction between cadmium or zinc and AMPSO was investigated by DCP and GEP, at fixed total ligand to total metal concentration ratios and various pH values, at 25.0\u2009\u00b0C and 0.1\u2005M KNO<jats:sub>3<\/jats:sub> ionic strength. For Cd\u2013(AMPSO)<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub>\u2013(OH)<jats:sub><jats:italic>y<\/jats:italic><\/jats:sub> system, CdL and CdL(OH) species, were identified, with stability constants values set to (as log\u2005<jats:italic>\u03b2<\/jats:italic>): 2.1\u00b10.1 and 6.2\u00b10.2, respectively. For Zn\u2013(AMPSO)<jats:sub><jats:italic>x<\/jats:italic><\/jats:sub>\u2013(OH)<jats:sub><jats:italic>y<\/jats:italic><\/jats:sub> system, the proposed final model with stability constants set to (as log\u2005<jats:italic>\u03b2<\/jats:italic>) is: ZnL=2.5\u00b10.1 and ZnL(OH)<jats:sub>2<\/jats:sub>=12.9\u00b10.2. For both systems, the fact that AMPSO deprotonation occurs in the metal hydrolysis and M(OH)<jats:sub>2<\/jats:sub> precipitation and the complexes formed are not too strong added a real challenge to data interpretation.<\/jats:p>","DOI":"10.1002\/elan.200503458","type":"journal-article","created":{"date-parts":[[2006,3,8]],"date-time":"2006-03-08T10:47:45Z","timestamp":1141814865000},"page":"719-729","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Complex Formation in the Region of Metal Hydrolysis and M(OH)<sub>2<\/sub> Precipitation. A Glass Electrode Potentiometric and Polarographic Study of Cd\u2013(AMPSO)<sub><i>x<\/i><\/sub>\u2013(OH)<sub><i>y<\/i><\/sub> and Zn\u2013(AMPSO)<sub><i>x<\/i><\/sub>\u2013(OH)<sub><i>y<\/i><\/sub> Systems"],"prefix":"10.1002","volume":"18","author":[{"given":"Carina\u2005M.\u2005M.","family":"Machado","sequence":"first","affiliation":[]},{"given":"Ignacy","family":"Cukrowski","sequence":"additional","affiliation":[]},{"given":"Helena\u2005M.\u2005V.\u2005M.","family":"Soares","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2006,4,11]]},"reference":[{"key":"e_1_2_1_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/hlca.200390270"},{"key":"e_1_2_1_2_2","doi-asserted-by":"publisher","DOI":"10.1021\/je0001779"},{"key":"e_1_2_1_3_2","doi-asserted-by":"publisher","DOI":"10.1007\/978-1-4899-1486-6"},{"key":"e_1_2_1_4_2","unstructured":"A.\u2005E. Martell R.\u2005M. Smith NIST Standard Reference Database 46 Version 8.0 NIST Critically Selected Stability Constants of Metal Complexes Database US Department of Commerce National Institute of Standards and Technology2004."},{"key":"e_1_2_1_5_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0003-2670(96)00335-2"},{"key":"e_1_2_1_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-0728(97)00145-9"},{"key":"e_1_2_1_7_2","doi-asserted-by":"publisher","DOI":"10.1016\/0039-9140(85)80261-7"},{"key":"e_1_2_1_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/0039-9140(88)80197-8"},{"key":"e_1_2_1_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/dt9850001195"},{"key":"e_1_2_1_10_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0003-2670(03)00816-X"},{"key":"e_1_2_1_11_2","unstructured":"R.\u2005M. Smith A.\u2005E. Martell NIST Standard Reference Database 46. NIST Critically Selected Stability Constants of Metal Complexes Database Version 3.0 US Department of Commerce National Institute of Standards and Technology1997."},{"volume-title":"Metrohm Application","year":"1975","key":"e_1_2_1_12_2"},{"key":"e_1_2_1_13_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.talanta.2005.06.003"},{"key":"e_1_2_1_14_2","unstructured":"C.\u2005M.\u2005M.Machado H.\u2005M.\u2005V.\u2005M.Soares unpublished results."}],"container-title":["Electroanalysis"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Felan.200503458","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/elan.200503458","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,15]],"date-time":"2025-10-15T17:39:32Z","timestamp":1760549972000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/elan.200503458"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2006,4]]},"references-count":14,"journal-issue":{"issue":"7","published-print":{"date-parts":[[2006,4]]}},"alternative-id":["10.1002\/elan.200503458"],"URL":"https:\/\/doi.org\/10.1002\/elan.200503458","archive":["Portico"],"relation":{},"ISSN":["1040-0397","1521-4109"],"issn-type":[{"type":"print","value":"1040-0397"},{"type":"electronic","value":"1521-4109"}],"subject":[],"published":{"date-parts":[[2006,4]]},"assertion":[{"value":"2005-11-23","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2006-01-25","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2006-04-11","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}