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Results suggest that the edge plane defects are kinetically dominant for the electro\u2010oxidation of nucleobases, whereas the basal plane sites are favoured for adsorption of the DNA to the electrode surface. For the high molecular weight DNA it is shown that although larger currents are obtained through the use of the edge plane electrode, it is beneficial in terms of signal\u2010to\u2010noise ratio to use a basal plane electrode.<\/jats:p>","DOI":"10.1002\/elan.201000637","type":"journal-article","created":{"date-parts":[[2011,1,12]],"date-time":"2011-01-12T09:52:41Z","timestamp":1294825961000},"page":"583-587","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":6,"title":["The Voltammetric Responses of High and Low Molecular Weight DNA on a Variety of Carbon Substrates; Demonstrating the Benefits of Graphitic Surfaces"],"prefix":"10.1002","volume":"23","author":[{"given":"Lu\u00eds M.","family":"Gon\u00e7alves","sequence":"first","affiliation":[]},{"given":"Christopher","family":"Batchelor\u2010McAuley","sequence":"additional","affiliation":[]},{"given":"Linhongjia","family":"Xiong","sequence":"additional","affiliation":[]},{"given":"Aquiles A.","family":"Barros","sequence":"additional","affiliation":[]},{"given":"Richard G.","family":"Compton","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2011,1,12]]},"reference":[{"key":"e_1_2_7_1_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.bios.2009.01.045"},{"key":"e_1_2_7_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.snb.2004.11.005"},{"key":"e_1_2_7_3_2","doi-asserted-by":"publisher","DOI":"10.1038\/188656a0"},{"key":"e_1_2_7_4_2","doi-asserted-by":"publisher","DOI":"10.1016\/0003-2697(88)90654-9"},{"key":"e_1_2_7_5_2","doi-asserted-by":"publisher","DOI":"10.1007\/0-387-24494-8_6"},{"key":"e_1_2_7_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.jelechem.2010.06.020"},{"key":"e_1_2_7_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ac015749m"},{"key":"e_1_2_7_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-0728(93)02994-S"},{"key":"e_1_2_7_9_2","doi-asserted-by":"publisher","DOI":"10.2116\/analsci.21.1263"},{"key":"e_1_2_7_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/b909734a"},{"key":"e_1_2_7_11_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.talanta.2007.10.012"},{"key":"e_1_2_7_12_2","doi-asserted-by":"publisher","DOI":"10.1039\/b406174h"},{"key":"e_1_2_7_13_2","doi-asserted-by":"publisher","DOI":"10.1039\/b413177k"},{"key":"e_1_2_7_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/elan.200900493"},{"key":"e_1_2_7_15_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp1021196"},{"key":"e_1_2_7_16_2","doi-asserted-by":"publisher","DOI":"10.1021\/jp1046672"},{"key":"e_1_2_7_17_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja9617855"},{"key":"e_1_2_7_18_2","unstructured":"As quoted from a communication with Sigma\u2010Aldrich."},{"key":"e_1_2_7_19_2","doi-asserted-by":"publisher","DOI":"10.1016\/S1567-5394(01)00147-5"},{"key":"e_1_2_7_20_2","doi-asserted-by":"publisher","DOI":"10.1016\/0022-0728(82)90006-7"},{"key":"e_1_2_7_21_2","doi-asserted-by":"publisher","DOI":"10.1142\/6430"},{"key":"e_1_2_7_22_2","doi-asserted-by":"publisher","DOI":"10.1006\/jcph.1997.5765"}],"container-title":["Electroanalysis"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Felan.201000637","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/elan.201000637","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,15]],"date-time":"2025-10-15T14:12:19Z","timestamp":1760537539000},"score":1,"resource":{"primary":{"URL":"https:\/\/analyticalsciencejournals.onlinelibrary.wiley.com\/doi\/10.1002\/elan.201000637"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2011,1,12]]},"references-count":22,"journal-issue":{"issue":"3","published-print":{"date-parts":[[2011,3]]}},"alternative-id":["10.1002\/elan.201000637"],"URL":"https:\/\/doi.org\/10.1002\/elan.201000637","archive":["Portico"],"relation":{},"ISSN":["1040-0397","1521-4109"],"issn-type":[{"type":"print","value":"1040-0397"},{"type":"electronic","value":"1521-4109"}],"subject":[],"published":{"date-parts":[[2011,1,12]]},"assertion":[{"value":"2010-10-13","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2010-11-03","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2011-01-12","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}]}}