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Cyclic voltammetry at the modified electrode in universal buffer showed a two electron oxidation\/reduction of the couple Mn\n                    <jats:sup>IV<\/jats:sup>\n                    (\u03bc\u2010O)\n                    <jats:sub>2<\/jats:sub>\n                    Mn\n                    <jats:sup>IV<\/jats:sup>\n                    \/Mn\n                    <jats:sup>III<\/jats:sup>\n                    (\u03bc\u2010O)\n                    <jats:sub>2<\/jats:sub>\n                    Mn\n                    <jats:sup>III<\/jats:sup>\n                    . The sensor exhibited electrocatalytic property toward sulfite oxidation with a decrease of the overpotential of 450\u2005mV compared with the glassy carbon electrode. A plot of the anodic current versus the sulfite concentration for potential fixed (+0.15\u2005V vs. SCE) at the sensor was linear in the 4.99\u00d710\n                    <jats:sup>\u22127<\/jats:sup>\n                    to 2.49\u00d710\n                    <jats:sup>\u22126<\/jats:sup>\n                    \u2005mol\u2009L\n                    <jats:sup>\u22121<\/jats:sup>\n                    concentration range and the concentration limit was 1.33\u00d710\n                    <jats:sup>\u22127<\/jats:sup>\n                    \u2005mol\u2009L\n                    <jats:sup>\u22121<\/jats:sup>\n                    . The mediated mechanism was derived by Michaelis\uf8ffMenten kinetics. The calculated kinetics values were Michaelis\uf8ffMenten rate constant=\n                    <jats:styled-content>\n                      ${K{{{\\rm app}\\hfill \\atop {\\rm M}\\hfill}}}$\n                      <jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/tex2gif-ueqn-1.gif\" xlink:title=\"equation image\"\/>\n                    <\/jats:styled-content>\n                    =1.33\u2005\u00b5mol\u2009L\n                    <jats:sup>\u22121<\/jats:sup>\n                    , catalytic rate constant=6.06\u00d710\n                    <jats:sup>\u22123<\/jats:sup>\n                    \u2005s\n                    <jats:sup>\u22121<\/jats:sup>\n                    and heterogeneous electro\u2010chemical rate constant=3.61\u00d710\n                    <jats:sup>\u22125<\/jats:sup>\n                    \u2005cm\u2009s\n                    <jats:sup>\u22121<\/jats:sup>\n                    .\n                  <\/jats:p>","DOI":"10.1002\/elan.201400289","type":"journal-article","created":{"date-parts":[[2014,9,18]],"date-time":"2014-09-18T16:02:32Z","timestamp":1411056152000},"page":"2182-2190","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Electrochemical Properties of the Oxo\u2010Manganese\u2010Phenanthroline Complex Immobilized on Ion\u2010Exchange Polymeric Film and Its Application as Biomimetic Sensor for Sulfite Ions"],"prefix":"10.1002","volume":"26","author":[{"given":"Wesley B. 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