{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,16]],"date-time":"2026-04-16T07:48:01Z","timestamp":1776325681368,"version":"3.50.1"},"reference-count":27,"publisher":"Wiley","issue":"5","license":[{"start":{"date-parts":[[2013,7,10]],"date-time":"2013-07-10T00:00:00Z","timestamp":1373414400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Fuel Cells"],"published-print":{"date-parts":[[2013,10]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>A series of glasses and glass\u2013ceramics (GCs) aiming at applications as sealants for solid oxide fuel cells (SOFCs) were synthesized by partial substitution of Ca for Sr in the diopside\u2010Ba disilicate composition. X\u2010ray diffraction in conjunction with the Rietveld\u2010RIR technique were employed to quantify the crystalline (diopside and Sr\u2010diopside) and amorphous phases in the glasses sintered\/heat treated at 850\u2009\u00b0C in humidified 10%H<jats:sub>2<\/jats:sub>\u201390%N<jats:sub>2<\/jats:sub> gas mixture for 250\u2009h. Weibull modulus varied in the range 11.6\u201334.4 implying toward good mechanical reliability of synthesized GCs. Thermal shock resistance of model electrochemical cells made of yttria\u2010stabilized zirconia, gadolinia\u2010doped ceria, and lanthanum gallate based solid electrolytes, hermetically sealed by one diopside\u2010based composition, was evaluated employing quenching from 800\u2009\u00b0C in air and water. Suitable thermal expansion coefficient, mechanical reliability, and strong adhesion to stabilized zirconia and metallic interconnects, are all suggesting a good suitability of the sealants for SOFC applications.<\/jats:p>","DOI":"10.1002\/fuce.201200237","type":"journal-article","created":{"date-parts":[[2013,7,10]],"date-time":"2013-07-10T07:27:48Z","timestamp":1373441268000},"page":"689-694","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":15,"title":["SrO\u2010Containing Diopside Glass\u2013Ceramic Sealants for Solid Oxide Fuel Cells: Mechanical Reliability and Thermal Shock Resistance"],"prefix":"10.1002","volume":"13","author":[{"given":"A. A.","family":"Reddy","sequence":"first","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"D. U.","family":"Tulyaganov","sequence":"additional","affiliation":[],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"M. 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