{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,19]],"date-time":"2026-03-19T12:24:46Z","timestamp":1773923086766,"version":"3.50.1"},"reference-count":38,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,3,19]],"date-time":"2026-03-19T00:00:00Z","timestamp":1773878400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc-nd\/4.0\/"},{"start":{"date-parts":[[2026,3,19]],"date-time":"2026-03-19T00:00:00Z","timestamp":1773878400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["scijournals.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Greenhouse Gases"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The development of membranes has evolved over the last years as an effective CO\n                    <jats:sub>2<\/jats:sub>\n                    separation technology to fight the environmental impact of post\u2010combustion processes. In this regard, the upgrade of conventional polymers has been approached through different strategies to overcome their permeance\u2010selectivity trade\u2010off. Mixed matrix membranes (MMMs) combine the benefits of fillers within a polymeric matrix to increase the CO\n                    <jats:sub>2<\/jats:sub>\n                    perm\u2010selectivity. More specifically, the coupling of metal\u2010organic frameworks (MOFs) with high CO\n                    <jats:sub>2<\/jats:sub>\n                    sorption capacity and CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010selective plasticizers, such as ionic liquids (ILs), has the potential to further improve the mechanical stability of membranes and their performance concerning CO\n                    <jats:sub>2<\/jats:sub>\n                    transport. In this work, Pebax1657\u2010based membranes combining the MOF ZIF\u20108 and 1\u2010ethyl\u20103\u2010methylimidazolium bis(trifluoromethanesulfonyl)imide ([EMIM][Tf\n                    <jats:sub>2<\/jats:sub>\n                    N]) IL have been optimized in terms of materials loading in a self\u2010standing framework. Then, their transition to a composite material using the spray\u2010coating technique has been addressed with a simple double\u2010step protocol, avoiding the need of an intermediate gutter layer. Composite membranes, as thin\u2010film composite (TFC) membranes, have the appeal of increasing the membrane permeance while maintaining the selectivity of self\u2010standing membranes. Here, it is described the capacity of the spray\u2010coating technique to convert advanced MMMs into TFC\u2010MMMs to further evaluate them in CO\n                    <jats:sub>2<\/jats:sub>\n                    separation processes.\n                  <\/jats:p>","DOI":"10.1002\/ghg.70025","type":"journal-article","created":{"date-parts":[[2026,3,19]],"date-time":"2026-03-19T08:25:19Z","timestamp":1773908719000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A New Method for Mixed Matrix Composite Membranes Preparation Using Direct Spray\u2010Coating Technique"],"prefix":"10.1002","author":[{"given":"Paloma","family":"Ortiz\u2010Albo","sequence":"first","affiliation":[{"name":"Department of Chemistry, LAQV\/REQUIMTE NOVA School of Science and Technology Universidade NOVA De Lisboa  Caparica Portugal"}]},{"given":"Juliette","family":"Tinevez","sequence":"additional","affiliation":[{"name":"ITECH Lyon  \u00c9cully France"}]},{"given":"Izumi","family":"Kumakiri","sequence":"additional","affiliation":[{"name":"Graduate School of Sciences and Technology for Innovation Yamaguchi University  Ube Japan"}]},{"given":"Jo\u00e3o","family":"Crespo","sequence":"additional","affiliation":[{"name":"Department of Chemistry, LAQV\/REQUIMTE NOVA School of Science and Technology Universidade NOVA De Lisboa  Caparica Portugal"},{"name":"ITQB Universidade NOVA De Lisboa  Oeiras Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9620-6286","authenticated-orcid":false,"given":"Lu\u00edsa A.","family":"Neves","sequence":"additional","affiliation":[{"name":"Department of Chemistry, LAQV\/REQUIMTE NOVA School of Science and Technology Universidade NOVA De Lisboa  Caparica Portugal"}]}],"member":"311","published-online":{"date-parts":[[2026,3,19]]},"reference":[{"key":"e_1_2_8_2_1","volume-title":"World Energy Outlook","author":"Energy Agency, 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