{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2023,11,5]],"date-time":"2023-11-05T02:40:48Z","timestamp":1699152048246},"reference-count":10,"publisher":"Wiley","issue":"3","license":[{"start":{"date-parts":[[2013,9,24]],"date-time":"2013-09-24T00:00:00Z","timestamp":1379980800000},"content-version":"vor","delay-in-days":14633,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["J Chinese Chemical Soc"],"published-print":{"date-parts":[[1973,9]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>In the radiolysis of cyclohexane in presence of 4\u00d710<jats:sup>\u22123<\/jats:sup><jats:italic>M<\/jats:italic> diphenylmercury (Hg \u03c6<jats:sub>3<\/jats:sub>) three isomers of hexane, methylcyclopentane (G=0.018), benzene (G=0.42) and cyclohexene (G=0.047) were detected. Addition of benzene in the mixture of cyclohexane and Hg \u03c6<jats:sub>3<\/jats:sub> formed two isomers of pentane, hexene and one isomer of hexane as additional products, while cyclohexene was eliminated completely. Normally, eight products were detected in presence of 10 to 50% benzene. Total radiolytic yield of products increased in presence of 15 to 25% benzene but in presence of 35 to 50% benzene G values became very low. Considerable amount of hexene is formed in a mixture of benzene and cyclohexane but neither benzene nor cyclohexane in presence of Hg \u03c6<jats:sub>2<\/jats:sub> formed this compound. In the presence o. benzene and \u03c6<jats:sub>2<\/jats:sub>Hg hexane yield is very much reduced. Protection is observed in presence of 10% as well as 35 to 50% benzene in this system. The plot of benzene concentration in moles\/litre versus methylcyclopentane is linear and from the slope of the straight line, the values of rate constants were found to be 2.65\u00d710<jats:sup>\u22122<\/jats:sup> litre\/mole sec., 5.25\u00d710<jats:sup>\u22123<\/jats:sup> litre mole sec., 9\u00d710<jats:sup>\u22127<\/jats:sup> litre\/mole sec. for methylcyclopentane, cyclohexane and benzene respectively. A plot of G(\u2013c\u2010C<jats:sub>6<\/jats:sub>H<jats:sub>12<\/jats:sub>) versus 1\/[C<jats:sub>6<\/jats:sub>H<jats:sub>6<\/jats:sub>] also gave a straight line which confirms the sponge type protection in this multicomponent system.<\/jats:p>","DOI":"10.1002\/jccs.197300015","type":"journal-article","created":{"date-parts":[[2015,6,4]],"date-time":"2015-06-04T16:07:59Z","timestamp":1433434079000},"page":"137-143","source":"Crossref","is-referenced-by-count":0,"title":["<sup>60<\/sup>Co\u2010<i>v<\/i> Radiolysis of a Mixture of Benzene and Cyclohexane in Presence of Diphenyl Mercury"],"prefix":"10.1002","volume":"20","author":[{"given":"S. B.","family":"Nazir","sequence":"first","affiliation":[]},{"given":"R. S.","family":"Rai","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2013,9,24]]},"reference":[{"key":"e_1_2_1_2_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0022-328X(00)87599-3"},{"key":"e_1_2_1_3_2","first-page":"2197","volume":"21","author":"Razuvaev G. A.","year":"1951","journal-title":"Zhuv. Obshchei Khim (J. Gen. Chem.)"},{"key":"e_1_2_1_4_2","first-page":"275","volume":"1","author":"Idam S. S.","year":"1963","journal-title":"Obshchei Khim, Akad. Nauk, S.S.S.R."},{"key":"e_1_2_1_5_2","unstructured":"Yu. A.Oldeltop Vchenye Zapiski Gor'kov. Univ.1953 No. 24 147\u201353."},{"key":"e_1_2_1_5_3","unstructured":"Refrat. Zhuv Khim1954 No. 28809."},{"key":"e_1_2_1_6_2","first-page":"371","volume":"141","author":"Razuvaev G. A.","year":"1961","journal-title":"Doklady Akad. Nauk S.S.S.R."},{"key":"e_1_2_1_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/j150576a009"},{"key":"e_1_2_1_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/j100815a011"},{"key":"e_1_2_1_9_2","doi-asserted-by":"publisher","DOI":"10.1063\/1.1726220"},{"key":"e_1_2_1_10_2","doi-asserted-by":"publisher","DOI":"10.2307\/3571104"}],"container-title":["Journal of the Chinese Chemical Society"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fjccs.197300015","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/jccs.197300015","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,11,5]],"date-time":"2023-11-05T02:26:43Z","timestamp":1699151203000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/jccs.197300015"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[1973,9]]},"references-count":10,"journal-issue":{"issue":"3","published-print":{"date-parts":[[1973,9]]}},"alternative-id":["10.1002\/jccs.197300015"],"URL":"https:\/\/doi.org\/10.1002\/jccs.197300015","archive":["Portico"],"relation":{},"ISSN":["0009-4536","2192-6549"],"issn-type":[{"value":"0009-4536","type":"print"},{"value":"2192-6549","type":"electronic"}],"subject":[],"published":{"date-parts":[[1973,9]]}}}