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In this paper, the kinetics of AA1050 temperature\u2010induced alcoholate pitting corrosion are examined experimentally with a specially constructed microreactor. The generated data are utilized to create a phase field model for the pit growth phase. The effects of ethanol\u2010blend composition and water content are quantitatively assessed and simulated. Phase field simulations allow for the first time the mechanistic characterization of the chemical corrosion process with a water content of up to 0.3% and an estimation of relevant reaction parameters at temperatures of up to 150\u00b0C. The approach can further be utilized to develop strategies for minimizing corrosion risk in\u2010service.<\/jats:p>","DOI":"10.1002\/maco.202414388","type":"journal-article","created":{"date-parts":[[2024,4,24]],"date-time":"2024-04-24T11:23:59Z","timestamp":1713957839000},"page":"1216-1227","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Mechanistic insights into chemical corrosion of AA1050 in ethanol\u2010blended fuels with water contamination via phase field modeling"],"prefix":"10.1002","volume":"75","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-6361-4275","authenticated-orcid":false,"given":"Eugen","family":"Gazenbiller","sequence":"first","affiliation":[{"name":"Institute of Surface Science Helmholtz\u2010Zentrum Hereon Geesthacht Germany"}]},{"given":"Visheet","family":"Arya","sequence":"additional","affiliation":[{"name":"Institute for Materials Technology (IfW) Technische Universit\u00e4t Darmstadt Darmstadt Germany"}]},{"given":"R\u00fcdiger","family":"Reitz","sequence":"additional","affiliation":[{"name":"Institute for Materials Technology (IfW) Technische Universit\u00e4t Darmstadt Darmstadt Germany"}]},{"given":"Matthias","family":"Oechsner","sequence":"additional","affiliation":[{"name":"Institute for Materials Technology (IfW) Technische Universit\u00e4t Darmstadt Darmstadt Germany"}]},{"given":"Mikhail L.","family":"Zheludkevich","sequence":"additional","affiliation":[{"name":"Institute of Surface Science Helmholtz\u2010Zentrum Hereon Geesthacht Germany"},{"name":"Faculty of Engineering Kiel University Kiel Germany"}]},{"given":"Daniel","family":"H\u00f6che","sequence":"additional","affiliation":[{"name":"Institute of Surface Science Helmholtz\u2010Zentrum Hereon Geesthacht Germany"}]}],"member":"311","published-online":{"date-parts":[[2024,4,24]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1007\/s10853-011-6108-1"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/mawe.201300028"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.fuel.2013.04.047"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/maco.201810125"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.corsci.2020.109137"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevE.86.051609"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41524-018-0089-4"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.electacta.2017.12.086"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.corsci.2017.12.027"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41598-018-31145-7"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevE.60.7186"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1744102"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/0001-6160(61)90182-1"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0045-7930(00)00031-1"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1359-6454(01)00118-5"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1146\/annurev.matsci.32.112001.132041"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1016\/0001-6160(79)90196-2"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.solidstatesciences.2007.03.022"},{"key":"e_1_2_9_20_1","first-page":"1293","volume":"29","author":"Wang W.","year":"2015","journal-title":"J. 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