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The different discharges observed in the TSDC spectrum have been analysed by the thermal sampling technique and have been attributed to specific relaxation mechanisms at the molecular level. A particular feature of the polymer studied in this work is that the mesogenic side group presents both longitudinal and transverse components of the dipole moment, and this seems to be at the origin of the presence of two separated relaxations in the liquid\u2010crystalline phase.<\/jats:p>","DOI":"10.1002\/macp.1995.021960717","type":"journal-article","created":{"date-parts":[[2003,4,17]],"date-time":"2003-04-17T10:05:02Z","timestamp":1050573902000},"page":"2289-2301","source":"Crossref","is-referenced-by-count":9,"title":["Molecular motions in a side\u2010chain liquid\u2010crystalline polymethacrylate. A thermally stimulated currents study of the dipolar relaxations in the vitreous and liquid\u2010crystalline phases and at the glass transition"],"prefix":"10.1002","volume":"196","author":[{"given":"Jo\u00e3o F.","family":"Mano","sequence":"first","affiliation":[]},{"given":"Nat\u00e1lia T.","family":"Correia","sequence":"additional","affiliation":[]},{"given":"Joaquim J. Moura","family":"Ramos","sequence":"additional","affiliation":[]},{"given":"David","family":"Coates","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2003,3,12]]},"reference":[{"key":"e_1_2_1_1_2","series-title":"Spec. Pub. No. 87","volume-title":"High Value Polymers","author":"Fawcett A. 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