{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,4]],"date-time":"2026-04-04T06:15:06Z","timestamp":1775283306886,"version":"3.50.1"},"reference-count":42,"publisher":"Wiley","issue":"11","license":[{"start":{"date-parts":[[2007,5,29]],"date-time":"2007-05-29T00:00:00Z","timestamp":1180396800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Macro Chemistry &amp; Physics"],"published-print":{"date-parts":[[2007,6,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Living radical polymerization of lauryl acrylate was achieved by SET\/DTLRP in water catalyzed by sodium dithionite. The work describes the synthesis of a highly hydrophobic and polar monomer in aqueous medium. The plots of <jats:styled-content>$\\overline M _{\\rm n}$<jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/tex2gif-ueqn-1.gif\" xlink:title=\"equation image\"\/><\/jats:styled-content> versus conversion and ln[M]<jats:sub>0<\/jats:sub>\/[M] versus time are linear, indicating a controlled polymerization. This method leads to <jats:italic>\u03b1<\/jats:italic>,<jats:italic>\u03c9<\/jats:italic>\u2010diiodopoly(lauryl acrylate)s that can be further functionalized. The MWDs were determined using a combination of three detectors: RALLS, DV, and RI. The method studied in this work represents a possible route to prepare well\u2010tailored macromolecules made of LA in environment friendly reaction medium. The syndiotactic content is 75%.<\/jats:p><jats:p><jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" mimetype=\"image\/gif\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic\/mgra001.gif\"><jats:alt-text>magnified image<\/jats:alt-text><\/jats:graphic><\/jats:boxed-text>\n<\/jats:p>","DOI":"10.1002\/macp.200700015","type":"journal-article","created":{"date-parts":[[2007,5,29]],"date-time":"2007-05-29T09:52:25Z","timestamp":1180432345000},"page":"1218-1227","source":"Crossref","is-referenced-by-count":41,"title":["Synthesis of Poly(lauryl acrylate) by Single\u2010Electron Transfer\/Degenerative Chain Transfer Living Radical Polymerization Catalyzed by Na<sub>2<\/sub>S<sub>2<\/sub>O<sub>4<\/sub> in Water"],"prefix":"10.1002","volume":"208","author":[{"given":"Jorge F. J.","family":"Coelho","sequence":"first","affiliation":[]},{"given":"Erica Y.","family":"Carvalho","sequence":"additional","affiliation":[]},{"given":"Dina S.","family":"Marques","sequence":"additional","affiliation":[]},{"given":"Anatoliy V.","family":"Popov","sequence":"additional","affiliation":[]},{"given":"Pedro M.","family":"Goncalves","sequence":"additional","affiliation":[]},{"given":"Maria H.","family":"Gil","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2007,5,29]]},"reference":[{"key":"e_1_2_5_1_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1097-4628(20000725)77:4<903::AID-APP26>3.0.CO;2-E"},{"key":"e_1_2_5_2_2","doi-asserted-by":"publisher","DOI":"10.1002\/mame.200500084"},{"key":"e_1_2_5_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.chroma.2005.04.083"},{"key":"e_1_2_5_4_2","doi-asserted-by":"publisher","DOI":"10.1080\/00222337008061005"},{"key":"e_1_2_5_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/pol.1976.180140709"},{"key":"e_1_2_5_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/app.20627"},{"key":"e_1_2_5_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma034409v"},{"key":"e_1_2_5_8_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma010011s"},{"key":"e_1_2_5_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma971444r"},{"key":"e_1_2_5_10_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma011714c"},{"key":"e_1_2_5_11_2","doi-asserted-by":"publisher","DOI":"10.1081\/MA-100103876"},{"key":"e_1_2_5_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/pola.20481"},{"key":"e_1_2_5_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja0256055"},{"key":"e_1_2_5_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/pola.10937"},{"key":"e_1_2_5_15_2","doi-asserted-by":"publisher","DOI":"10.1002\/pola.20604"},{"key":"e_1_2_5_16_2","volume":"43","author":"Percec V.","year":"2005","journal-title":"J. Polym. Sci., Part A: Polym. Chem."},{"key":"e_1_2_5_17_2","unstructured":"V.Percec T.Guliashvili A. V.Popov (University of Pennsylvania). U.S. Patent Appl Publ 2005\/0131186 Chem. Abstr.2005 143 60398."},{"key":"e_1_2_5_18_2","doi-asserted-by":"publisher","DOI":"10.1002\/pola.20655"},{"key":"e_1_2_5_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/pola.20482"},{"key":"e_1_2_5_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/pola.21389"},{"key":"e_1_2_5_21_2","doi-asserted-by":"publisher","DOI":"10.1002\/pola.21403"},{"key":"e_1_2_5_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/vnl.20088"},{"key":"e_1_2_5_23_2","unstructured":"J. F. J.Coelho PhD Thesis University of Coimbra2006."},{"key":"e_1_2_5_24_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.eurpolymj.2006.05.023"},{"key":"e_1_2_5_25_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0032-3861(02)00461-5"},{"key":"e_1_2_5_26_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0144-8617(99)00017-X"},{"key":"e_1_2_5_27_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.eurpolymj.2005.09.023"},{"key":"e_1_2_5_28_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma034892"},{"key":"e_1_2_5_29_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma00128a012"},{"key":"e_1_2_5_30_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma9712007"},{"key":"e_1_2_5_31_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma990447w"},{"key":"e_1_2_5_32_2","doi-asserted-by":"publisher","DOI":"10.1002\/pola.10309"},{"key":"e_1_2_5_33_2","doi-asserted-by":"crossref","DOI":"10.1201\/9780585139401","volume-title":"Anionic Polymerization Principles and Practical Applications","author":"Hsieh H. L.","year":"1996"},{"key":"e_1_2_5_34_2","doi-asserted-by":"publisher","DOI":"10.1021\/ma00110a050"},{"key":"e_1_2_5_35_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0079-6700(01)00033-8"},{"key":"e_1_2_5_36_2","first-page":"117","volume-title":"Handbook of Radical Chemistry","author":"Yamada B.","year":"2002"},{"key":"e_1_2_5_37_2","doi-asserted-by":"publisher","DOI":"10.1002\/(SICI)1099-0518(19980115)36:1<IX::AID-POLA2>3.0.CO;2-9"},{"key":"e_1_2_5_38_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01592a101"},{"key":"e_1_2_5_39_2","doi-asserted-by":"publisher","DOI":"10.1038\/1781168a0"},{"key":"e_1_2_5_40_2","volume-title":"Polymer Handbook","author":"Brandrup J.","year":"1989"},{"key":"e_1_2_5_41_2","unstructured":"TriSEC GPC Software Manual; V. Corp. Ed.1996 p.A2."},{"key":"e_1_2_5_42_2","doi-asserted-by":"publisher","DOI":"10.1016\/j.ijpharm.2005.11.019"}],"container-title":["Macromolecular Chemistry and Physics"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fmacp.200700015","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/macp.200700015","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,10]],"date-time":"2023-10-10T08:27:45Z","timestamp":1696926465000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/macp.200700015"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2007,5,29]]},"references-count":42,"journal-issue":{"issue":"11","published-print":{"date-parts":[[2007,6,4]]}},"alternative-id":["10.1002\/macp.200700015"],"URL":"https:\/\/doi.org\/10.1002\/macp.200700015","archive":["Portico"],"relation":{},"ISSN":["1022-1352","1521-3935"],"issn-type":[{"value":"1022-1352","type":"print"},{"value":"1521-3935","type":"electronic"}],"subject":[],"published":{"date-parts":[[2007,5,29]]}}}