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In this vein, in this study, an original renewable 2,5\u2010furandicarboxylic acid\u2010based cycloaliphatic homopolyester, poly(1,4\u2010cyclohexylene 2,5\u2010furandicarboxylate) (PCdF), is synthesized from dimethyl\u20102,5\u2010furandicarboxylate and 1,4\u2010cyclohexanediol. Poly(1,4\u2010cyclohexanedimethylene 2,5\u2010furandicarboxylate) is also prepared for comparison purposes, since it is the direct renewable substitute of poly(1,4\u2010cyclohexanedimethylene terephthalate) and they are structurally related. The resulting homopolyesters are characterized in detail by using attenuated total reflectance Fourier transform infrared, <jats:sup>1<\/jats:sup>H, <jats:sup>13<\/jats:sup>C and 2D NMR, X\u2010ray and elemental analysis, and thermal properties are assessed by thermogravimetric analysis, differential scanning calorimetry, and dynamic mechanical thermal analysis. PCdF shows to have a semicrystalline character, exhibiting an extremely high glass transition temperature around 175 \u00b0C. Moreover, this polyester also shows to be a high thermally stable material with a degradation temperature of 380.0 \u00b0C.\n<jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" mimetype=\"image\/png\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic\/macp201600492-abs-0001-m.png\"><jats:alt-text>image<\/jats:alt-text><\/jats:graphic><\/jats:boxed-text><\/jats:p>","DOI":"10.1002\/macp.201600492","type":"journal-article","created":{"date-parts":[[2016,12,30]],"date-time":"2016-12-30T16:07:15Z","timestamp":1483114035000},"source":"Crossref","is-referenced-by-count":33,"title":["Improving the Thermal Properties of Poly(2,5\u2010furandicarboxylate)s Using Cyclohexylene Moieties: A Comparative Study"],"prefix":"10.1002","volume":"218","author":[{"given":"Marina","family":"Matos","sequence":"first","affiliation":[{"name":"CICECO and Department of Chemistry University of Aveiro  3810\u2010193 Aveiro Portugal"}]},{"given":"Andreia F.","family":"Sousa","sequence":"additional","affiliation":[{"name":"CICECO and Department of Chemistry University of Aveiro  3810\u2010193 Aveiro Portugal"},{"name":"CEMUC Department of Chemical Engineering University of Coimbra  3030\u2010790 Coimbra Portugal"}]},{"given":"Armando J. 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