{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,1]],"date-time":"2026-04-01T13:16:56Z","timestamp":1775049416147,"version":"3.50.1"},"reference-count":27,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2013,11,29]],"date-time":"2013-11-29T00:00:00Z","timestamp":1385683200000},"content-version":"vor","delay-in-days":28,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Macromolecular Symposia"],"published-print":{"date-parts":[[2013,11]]},"abstract":"<jats:title>Summary<\/jats:title><jats:sec><jats:label\/><jats:p>Experimental studies concerning the RAFT copolymerization of styrene and commercial divinylbenzene were performed in order to assess the use of controlled radical polymerization for the production of non\u2010conventional polymer networks. Aqueous suspension polymerizations were carried out in stirred batch reactor and changes of a few operation parameters were tried in order to assess their effect on key product properties: reaction temperature, initial ratio monomer\/RAFT agent, monomer dilution in the organic phase and crosslinker content in the monomer mixture were changed along the experimental program. Polymerizations were extended beyond the gel point in order to synthesize gel beads. The effect of different commercially available RAFT agents (e.g. S\u2010thiobenzoyl thioglycolic acid and two trithiocarbonates) on network process formation was also studied. Dynamics of gel formation was measured using size exclusion chromatography with refractive index and light scattering detection. Iodine chloride titration yielded pendant double bonds concentration. <jats:italic>In\u2010line<\/jats:italic> and <jats:italic>off\u2010line<\/jats:italic> FTIR\u2010ATR measurements were also performed in order to obtain information concerning the kinetics of formation and final structure of the gels.<\/jats:p><\/jats:sec>","DOI":"10.1002\/masy.201300046","type":"journal-article","created":{"date-parts":[[2013,11,29]],"date-time":"2013-11-29T07:41:29Z","timestamp":1385710889000},"page":"273-285","source":"Crossref","is-referenced-by-count":11,"title":["Dynamics of Network Formation in Aqueous Suspension <scp>RAFT<\/scp> Styrene\/<scp>D<\/scp>ivinylbenzene Copolymerization"],"prefix":"10.1002","volume":"333","author":[{"given":"Miguel A. D.","family":"Gon\u00e7alves","sequence":"first","affiliation":[{"name":"LSRE\u2010Instituto Polit\u00e9cnico de Bragan\u00e7a Quinta de Santa Apol\u00f3nia 5300 Bragan\u00e7a Portugal"}]},{"given":"Virg\u00ednia D.","family":"Pinto","sequence":"additional","affiliation":[{"name":"LSRE\u2010Instituto Polit\u00e9cnico de Bragan\u00e7a Quinta de Santa Apol\u00f3nia 5300 Bragan\u00e7a Portugal"}]},{"given":"Rolando C. S.","family":"Dias","sequence":"additional","affiliation":[{"name":"LSRE\u2010Instituto Polit\u00e9cnico de Bragan\u00e7a Quinta de Santa Apol\u00f3nia 5300 Bragan\u00e7a Portugal"}]},{"given":"Julio C.","family":"Hern\u00e1ndes\u2010Ortiz","sequence":"additional","affiliation":[{"name":"LSRE\u2010Faculdade de Engenharia da Universidade do Porto Rua Roberto Frias s\/n 4200\u2010465 Porto Portugal"}]},{"given":"M\u00e1rio Rui P. F. N.","family":"Costa","sequence":"additional","affiliation":[{"name":"LSRE\u2010Faculdade de Engenharia da Universidade do Porto Rua Roberto Frias s\/n 4200\u2010465 Porto Portugal"}]}],"member":"311","published-online":{"date-parts":[[2013,11,29]]},"reference":[{"key":"e_1_2_5_1_1","doi-asserted-by":"publisher","DOI":"10.1071\/CH12295"},{"key":"e_1_2_5_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2006.11.002"},{"key":"e_1_2_5_3_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.progpolymsci.2007.11.002"},{"key":"e_1_2_5_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr800242x"},{"key":"e_1_2_5_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma991866w"},{"key":"e_1_2_5_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma002130y"},{"key":"e_1_2_5_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/macp.200700464"},{"key":"e_1_2_5_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.polymer.2009.05.032"},{"key":"e_1_2_5_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma051747i"},{"key":"e_1_2_5_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma070614p"},{"key":"e_1_2_5_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie901515t"},{"key":"e_1_2_5_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie901143p"},{"key":"e_1_2_5_13_1","doi-asserted-by":"publisher","DOI":"10.1021\/ie070357c"},{"key":"e_1_2_5_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/ma202215s"},{"key":"e_1_2_5_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/aic.13890"},{"key":"e_1_2_5_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/ceat.201000257"},{"key":"e_1_2_5_17_1","doi-asserted-by":"publisher","DOI":"10.1071\/CH12291"},{"key":"e_1_2_5_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/mren.201200058"},{"key":"e_1_2_5_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/masy.201051031"},{"key":"e_1_2_5_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/masy.200751315"},{"key":"e_1_2_5_21_1","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-08-091740-5.50014-4"},{"key":"e_1_2_5_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jp970620v"},{"key":"e_1_2_5_23_1","volume-title":"Experimentelle Untersuchungen und Monte\u2010Carlo\u2010Simulation netzwerkbildender Copolymerisationen","author":"Hecker M.","year":"2000"},{"key":"e_1_2_5_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/mren.201100071"},{"key":"e_1_2_5_25_1","volume-title":"Synthesis of styrene\u2010divinylbenzene copolymers using free radical and nitroxide mediated polymerization: experiments and mathematical modelling","author":"Aguiar L. G.","year":"2013"},{"key":"e_1_2_5_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/mren.201300105"},{"key":"e_1_2_5_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/mats.201100023"}],"container-title":["Macromolecular Symposia"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fmasy.201300046","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fmasy.201300046","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/masy.201300046","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,13]],"date-time":"2023-09-13T09:32:51Z","timestamp":1694597571000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/masy.201300046"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2013,11]]},"references-count":27,"journal-issue":{"issue":"1","published-print":{"date-parts":[[2013,11]]}},"alternative-id":["10.1002\/masy.201300046"],"URL":"https:\/\/doi.org\/10.1002\/masy.201300046","archive":["Portico"],"relation":{},"ISSN":["1022-1360","1521-3900"],"issn-type":[{"value":"1022-1360","type":"print"},{"value":"1521-3900","type":"electronic"}],"subject":[],"published":{"date-parts":[[2013,11]]}}}