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A rather complex kinetic scheme involving crosslinking and long\u2010chain branching is considered. It is shown that even in these conditions it is possible to carry out the prediction of molecular size and mass distributions, sequence size distributions, and <jats:italic>z<\/jats:italic>\u2010average mean\u2010square radius of gyration of the polymers. The influence of some kinetic parameters on the properties of the products is studied, considering a homogeneous operation in a semi\u2010batch reactor. 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