{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,2]],"date-time":"2026-01-02T07:36:21Z","timestamp":1767339381565},"reference-count":17,"publisher":"Wiley","issue":"4","license":[{"start":{"date-parts":[[2013,7,11]],"date-time":"2013-07-11T00:00:00Z","timestamp":1373500800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"funder":[{"name":"Marie Curie Initial Training Network \u201cNanopoly\u201d:","award":["ITN-GA-2009-238700"],"award-info":[{"award-number":["ITN-GA-2009-238700"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Macro Reaction Engineering"],"published-print":{"date-parts":[[2014,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:sec><jats:label \/><jats:p>A kinetic model including the cyclic propagation (cyclization) is proposed for the nitroxide\u2010mediated radical copolymerization of styrene\u2013divinylbenzene. The method involves a balance of sequences of units, which connect a radical center and a pendant double bond present in the same polymer chain. The rate constant for cyclization was considered a function of the sequence length. Good agreement between the model predictions and experimental data for solution and suspension controlled copolymerizations was found. The rate constant of cyclization for the smallest ring (3 monomeric units) was estimated to be 700\u2009s<jats:sup>\u22121<\/jats:sup> at 90\u2009\u00b0C, and the activation energy was estimated to be 32\u2009500\u2009cal\u2009mol<jats:sup>\u22121<\/jats:sup>.<jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/mren201300105-gra-0001.png\" xlink:title=\"mren201300105-gra-0001\" \/><\/jats:p><\/jats:sec>","DOI":"10.1002\/mren.201300105","type":"journal-article","created":{"date-parts":[[2013,7,11]],"date-time":"2013-07-11T11:02:57Z","timestamp":1373540577000},"page":"282-294","source":"Crossref","is-referenced-by-count":22,"title":["Development of Cyclic Propagation Kinetics for Modeling the Nitroxide\u2010mediated Radical Copolymerization of Styrene\u2013<scp>D<\/scp>ivinylbenzene"],"prefix":"10.1002","volume":"8","author":[{"given":"Leandro G.","family":"Aguiar","sequence":"first","affiliation":[{"name":"Escola Polit\u00e9cnica da Universidade de S\u00e3o Paulo Departamento de Engenharia Qu\u00edmica. Av. Prof. Luciano Gualberto travessa 3, No. 380 05508\u2010010\u2013S\u00e3o Paulo SP, Brasil USA"}]},{"given":"Miguel A. D.","family":"Gon\u00e7alves","sequence":"additional","affiliation":[{"name":"LSRE \u2013 Instituto Polit\u00e9cnico de Bragan\u00e7a Quinta de Santa Apol\u00f4nia 5300 Bragan\u00e7a Portugal"}]},{"given":"Virg\u00ednia D.","family":"Pinto","sequence":"additional","affiliation":[{"name":"LSRE \u2013 Instituto Polit\u00e9cnico de Bragan\u00e7a Quinta de Santa Apol\u00f4nia 5300 Bragan\u00e7a Portugal"}]},{"given":"Rolando C. S.","family":"Dias","sequence":"additional","affiliation":[{"name":"LSRE \u2013 Instituto Polit\u00e9cnico de Bragan\u00e7a Quinta de Santa Apol\u00f4nia 5300 Bragan\u00e7a Portugal"}]},{"given":"M\u00e1rio Rui P. F. 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