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Cyclization reactions are tackled by balances of sequences, yielding fair predictions of the measured pendant double bond concentration. With reduction in crosslinking, agreement for the experiments at 90\u2009\u00b0C between predicted and measured weight\u2010average, molecular weight, and weight fraction of gel is observed. A much higher relative crosslinking reactivity is observed at 130\u2009\u00b0C as compared to 90\u2009\u00b0C, likely an effect of the chain mobility.<jats:inline-graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" xlink:href=\"graphic\/mren201300171-gra-0001.png\" xlink:title=\"mren201300171-gra-0001\" \/><\/jats:p><\/jats:sec>","DOI":"10.1002\/mren.201300171","type":"journal-article","created":{"date-parts":[[2013,11,29]],"date-time":"2013-11-29T07:46:50Z","timestamp":1385711210000},"page":"295-313","source":"Crossref","is-referenced-by-count":22,"title":["Mathematical Modeling of <scp>NMRP<\/scp> of Styrene\u2013<scp>D<\/scp>ivinylbenzene over the Pre\u2010 and Post\u2010<scp>G<\/scp>elation Periods Including Cyclization"],"prefix":"10.1002","volume":"8","author":[{"given":"Leandro G.","family":"Aguiar","sequence":"first","affiliation":[{"name":"Escola Polit\u00e9cnica da Universidade de S\u00e3o Paulo Departamento de Engenharia Qu\u00edmica. Av. 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