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The functionalization of the materials with pyridyl groups was confirmed by FTIR and the SEM micrographs of the hybrid particles demonstrate a clear surface modification compared with the pristine cellulose. Competitive sorption\/desorption testing of the imprinted and non\u2010imprinted particles with standard polyphenols show the achievement of an imprinting factor IF \u223c8. Moreover, it was also confirmed the high retention capability of the hybrid materials for polyphenols, due to their strong binding with the surface pyridyl moieties, even when using hydroalcoholic solvents of high ethanol content (e.g., ethanol\/water 80\/20 v\/v). The sorption capabilities of the synthesized materials for polyphenols were explored with the fractionation of flavonols and anthocyanins in winemaking residues. High concentration and enrichment factors were achieved for high\u2010added value compounds, namely five times for quercetin and 12 for quercetin\u20103\u2010O\u2010glucuronide with a diatomaceous earth extract and up to 4 for flavonols in a grape pomace (e.g. myricetin and quercetin glucosides). This research demonstrates the feasibility for the combination between the development of engineered materials addressing sustainability with their application to the valorization of agro\u2010industrial wastes.<\/jats:p>","DOI":"10.1002\/nano.202300153","type":"journal-article","created":{"date-parts":[[2024,2,8]],"date-time":"2024-02-08T07:00:44Z","timestamp":1707375644000},"source":"Crossref","is-referenced-by-count":5,"title":["Fractionation of flavonols and anthocyanins in winemaking residues using molecularly imprinted cellulose\u2010synthetic hybrid particles with pyridyl active surface"],"prefix":"10.1002","volume":"5","author":[{"given":"Catarina P.","family":"Gomes","sequence":"first","affiliation":[{"name":"Centro de Investiga\u00e7\u00e3o de Montanha (CIMO) Instituto Polit\u00e9cnico de Bragan\u00e7a  Bragan\u00e7a Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7369-382X","authenticated-orcid":false,"given":"Rolando C. 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