{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,5,9]],"date-time":"2025-05-09T16:34:13Z","timestamp":1746808453084,"version":"3.40.5"},"reference-count":26,"publisher":"Wiley","issue":"8","license":[{"start":{"date-parts":[[2005,4,7]],"date-time":"2005-04-07T00:00:00Z","timestamp":1112832000000},"content-version":"vor","delay-in-days":6459,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Org. Mass Spectrom."],"published-print":{"date-parts":[[1987,8]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Primary fragmentation reactions in benzohydroxamic and benzothiohydroxamic acids have been studied and compared with those in benzamides and benzothioamides. Mass\u2010analysed ion kinetic energy spectra, collisional activation spectra and spectral data from labelled compounds were used to elucidate fragment ion structures and reaction mechanisms. The mass spectra are shown to be dependent on ion source temperature. Losses of O and H<jats:sub>2<\/jats:sub>O are proved to be thermal in origin. The formation of an S\u2026 HO bond, which is analogous to an intramolecular hydrogen bond in solution chemistry, directs many fragmentation pathways. This seems to be the major factor determining the differences between the mass spectra of benzothiohydroxamic acids and those of the corresponding carbonyl compounds.<\/jats:p>","DOI":"10.1002\/oms.1210220806","type":"journal-article","created":{"date-parts":[[2005,5,28]],"date-time":"2005-05-28T08:21:21Z","timestamp":1117268481000},"page":"506-512","source":"Crossref","is-referenced-by-count":4,"title":["The mass spectrometric behaviour of benzohydroxaraic and benzothiohydroxamic acids under electron impact"],"prefix":"10.1002","volume":"22","author":[{"given":"M. H.","family":"Flor\u011bncio","sequence":"first","affiliation":[]},{"given":"W.","family":"Heerma","sequence":"additional","affiliation":[]},{"given":"M. A.","family":"Santos","sequence":"additional","affiliation":[]},{"given":"M. R.","family":"Tavares","sequence":"additional","affiliation":[]},{"given":"A. M.","family":"Lobo","sequence":"additional","affiliation":[]},{"given":"S.","family":"Prabhakar","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2005,4,7]]},"reference":[{"key":"e_1_2_1_2_2","doi-asserted-by":"crossref","unstructured":"W.WalterandE.Schaumann Synthesis 111(1971).","DOI":"10.1055\/s-1971-21676"},{"key":"e_1_2_1_3_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4039(00)94229-1"},{"key":"e_1_2_1_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.197403761"},{"key":"e_1_2_1_5_2","doi-asserted-by":"crossref","first-page":"97","DOI":"10.1002\/bscb.19800890203","volume":"89","author":"Agrawal Y. K.","year":"1980","journal-title":"Bull. Soc. Chim. Belg."},{"key":"e_1_2_1_6_2","doi-asserted-by":"publisher","DOI":"10.1002\/oms.1210100404"},{"key":"e_1_2_1_7_2","doi-asserted-by":"publisher","DOI":"10.3891\/acta.chem.scand.21-1936"},{"key":"e_1_2_1_8_2","doi-asserted-by":"crossref","first-page":"1511","DOI":"10.1039\/p29840001511","volume":"2","author":"Lobo A. M.","year":"1984","journal-title":"J. Chem. Soc., Perkin Trans."},{"key":"e_1_2_1_9_2","doi-asserted-by":"publisher","DOI":"10.1039\/P29800001051"},{"key":"e_1_2_1_10_2","doi-asserted-by":"publisher","DOI":"10.1071\/CH9690175"},{"key":"e_1_2_1_11_2","doi-asserted-by":"publisher","DOI":"10.1002\/oms.1210030113"},{"key":"e_1_2_1_12_2","doi-asserted-by":"publisher","DOI":"10.1002\/oms.1210171214"},{"key":"e_1_2_1_13_2","doi-asserted-by":"publisher","DOI":"10.1002\/oms.1210120316"},{"key":"e_1_2_1_14_2","doi-asserted-by":"publisher","DOI":"10.1002\/oms.1210170304"},{"volume-title":"The Mass Spectra of Organic Molecules","year":"1968","author":"Beynon J. H.","key":"e_1_2_1_15_2"},{"key":"e_1_2_1_16_2","doi-asserted-by":"publisher","DOI":"10.1002\/oms.1210170904"},{"key":"e_1_2_1_17_2","doi-asserted-by":"publisher","DOI":"10.1002\/oms.1210110706"},{"key":"e_1_2_1_17_3","first-page":"5","volume-title":"Comprehensive Organic Chemistry","author":"Barrett G. C.","year":"1979"},{"key":"e_1_2_1_18_2","doi-asserted-by":"crossref","first-page":"418","DOI":"10.1002\/oms.1210181003","volume":"18","author":"Ramana D. V.","year":"1983","journal-title":"Org. Mass Spectrom."},{"key":"e_1_2_1_19_2","doi-asserted-by":"publisher","DOI":"10.1002\/oms.1210150802"},{"key":"e_1_2_1_20_2","doi-asserted-by":"publisher","DOI":"10.1002\/oms.1210050504"},{"key":"e_1_2_1_21_2","doi-asserted-by":"publisher","DOI":"10.1246\/bcsj.58.2798"},{"key":"e_1_2_1_22_2","doi-asserted-by":"publisher","DOI":"10.1002\/bms.1200121006"},{"key":"e_1_2_1_23_2","doi-asserted-by":"crossref","unstructured":"S.Prabhakar A. M.Lobo M. A.SantosandH. S.Rzepa Synthesis 829(1984).","DOI":"10.1055\/s-1984-30981"},{"key":"e_1_2_1_24_2","doi-asserted-by":"publisher","DOI":"10.1002\/bscb.19780870311"},{"key":"e_1_2_1_25_2","doi-asserted-by":"publisher","DOI":"10.1021\/je60032a046"},{"key":"e_1_2_1_26_2","doi-asserted-by":"publisher","DOI":"10.1002\/oms.1210160712"}],"container-title":["Organic Mass Spectrometry"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Foms.1210220806","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/oms.1210220806","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,10,20]],"date-time":"2023-10-20T14:44:53Z","timestamp":1697813093000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/oms.1210220806"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[1987,8]]},"references-count":26,"journal-issue":{"issue":"8","published-print":{"date-parts":[[1987,8]]}},"alternative-id":["10.1002\/oms.1210220806"],"URL":"https:\/\/doi.org\/10.1002\/oms.1210220806","archive":["Portico"],"relation":{},"ISSN":["0030-493X"],"issn-type":[{"type":"print","value":"0030-493X"}],"subject":[],"published":{"date-parts":[[1987,8]]}}}