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The controlled polymerization of polymer shells onto Au nanoparticles is attempted by using the macroRAFT (MR) agent based on 2\u2010(dodecylthiocarbonothioylthio)\u20102\u2010methylpropionic acid synthesized via RAFT polymerization of poly(ethylene glycol) methyl ether acrylate and exploring several approaches, which include (i) post\u2010modification; (ii) <jats:italic>in situ<\/jats:italic> synthesis and (iii) \u201cgrafting from\u201d strategies. In the conditions investigated here all these strategies lead to Au polymer nanocomposites but morphological well\u2010defined core\u2010shell nanoparticles are only obtained by applying the \u201cgrafting from\u201d strategy. In particular, conditions that promote chain extension from the MR agent adsorbed onto the Au nanoparticles are found necessary to obtain nanostructures with such morphological characteristics and that still show the localized surface plasmon resonance typical of colloidal Au nanoparticles.<\/jats:p>","DOI":"10.1002\/ppsc.201600202","type":"journal-article","created":{"date-parts":[[2016,11,7]],"date-time":"2016-11-07T12:21:26Z","timestamp":1478521286000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["A Comparative Study of Chemical Routes for Coating Gold Nanoparticles via Controlled RAFT Emulsion Polymerization"],"prefix":"10.1002","volume":"34","author":[{"given":"S\u00f3nia O.","family":"Pereira","sequence":"first","affiliation":[{"name":"Department of Chemistry CICECO\u2010 Aveiro Institute of Materials University of Aveiro  3810\u2010193 Aveiro 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