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It is shown that the (Ca, Mn)\u2010doped samples maintain the polar <jats:italic>R3c<\/jats:italic> structure characteristic of the pure bismuth ferrite. For both these compounds, an antiferromagnetic (AFM) G\u2010type ordering of the Fe\/Mn magnetic moments along the hexagonal <jats:italic>c<\/jats:italic>\u2010axis is revealed at room temperature. The reorientation of the magnetic moments from the <jats:italic>c\u2010<\/jats:italic> to <jats:italic>a<\/jats:italic>\u2010axis occurs as temperature decreases. Being consistent with the competing character of the superexchange between Mn<jats:sup>3+<\/jats:sup>, Mn<jats:sup>4+<\/jats:sup>, and Fe<jats:sup>3+<\/jats:sup> ions, the coexistence of AFM long\u2010range\u2010ordered and superparamagnetic phases underlying the appearance of a significant magnetization in the low\u2010temperature range is observed.<\/jats:p><\/jats:sec>","DOI":"10.1002\/pssb.202000121","type":"journal-article","created":{"date-parts":[[2020,4,22]],"date-time":"2020-04-22T10:27:33Z","timestamp":1587551253000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Increased Low\u2010Temperature Magnetization and Spin\u2010Reorientational Transition in the Polar Phase of (Ca, Mn)\u2010Doped Bismuth Ferrites"],"prefix":"10.1002","volume":"257","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5867-3297","authenticated-orcid":false,"given":"Vladimir A.","family":"Khomchenko","sequence":"first","affiliation":[{"name":"Department of Physics CFisUC University of Coimbra  Coimbra P-3004-516 Portugal"}]},{"given":"Maxim V.","family":"Silibin","sequence":"additional","affiliation":[{"name":"National Research University of Electronic Technology \u201cMIET\u201d  Zelenograd Moscow 124498 Russia"},{"name":"Institute for Bionic Technologies and Engineering I. 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