{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,16]],"date-time":"2026-03-16T15:47:45Z","timestamp":1773676065556,"version":"3.50.1"},"reference-count":0,"publisher":"Wiley","issue":"9","license":[{"start":{"date-parts":[[2010,6,10]],"date-time":"2010-06-10T00:00:00Z","timestamp":1276128000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Phys. Status Solidi (c)"],"published-print":{"date-parts":[[2010,9]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Polycrystalline Zn<jats:sub>3<\/jats:sub>N<jats:sub>2<\/jats:sub> films were prepared on sapphire and quartz substrates by reactive pulsed laser ablation of a metallic zinc target in a nitrogen plasma atmosphere using a frequency\u2010doubled Nd:YAG laser, assisted by a 13.56 MHz radio\u2010frequency (RF) plasma. The morphological, structural and optical properties are studied by Scanning Electron Microscopy, X\u2010ray diffraction, transmittance and ellipsometric spectroscopy. SEM revealed a very smooth and crack\u2010free film surface. X\u2010ray diffraction indicates that the Zn<jats:sub>3<\/jats:sub>N<jats:sub>2<\/jats:sub> films deposited at 400 \u00b0C substrate temperature are cubic in structure with no preferred orientation. The lattice constant has been estimated to be a = 0.97 nm. The absorption coefficient is deduced from the transmission spectra, and its dependence on photon energy is examined to determine the optical band gap. Refractive index and film thickness are deduced from spectroscopic ellipsometry measurements. Zn<jats:sub>3<\/jats:sub>N<jats:sub>2<\/jats:sub> is determined to be a n\u2010type semiconductor with a direct band gap of 3.2 eV. (\u00a9 2010 WILEY\u2010VCH Verlag GmbH &amp; Co. KGaA, Weinheim)<\/jats:p>","DOI":"10.1002\/pssc.200983733","type":"journal-article","created":{"date-parts":[[2010,6,10]],"date-time":"2010-06-10T12:02:30Z","timestamp":1276171350000},"page":"2294-2297","source":"Crossref","is-referenced-by-count":25,"title":["RF\u2010plasma assisted PLD growth of Zn<sub>3<\/sub>N<sub>2<\/sub> thin films"],"prefix":"10.1002","volume":"7","author":[{"given":"Rachid","family":"Ayouchi","sequence":"first","affiliation":[]},{"given":"Catarina","family":"Casteleiro","sequence":"additional","affiliation":[]},{"given":"Luis","family":"Santos","sequence":"additional","affiliation":[]},{"given":"Reinhard","family":"Schwarz","sequence":"additional","affiliation":[]}],"member":"311","published-online":{"date-parts":[[2010,6,10]]},"container-title":["physica status solidi c"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/api.wiley.com\/onlinelibrary\/tdm\/v1\/articles\/10.1002%2Fpssc.200983733","content-type":"unspecified","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/pssc.200983733","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/pssc.200983733","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2023,9,12]],"date-time":"2023-09-12T14:26:00Z","timestamp":1694528760000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/pssc.200983733"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2010,6,10]]},"references-count":0,"journal-issue":{"issue":"9","published-print":{"date-parts":[[2010,9]]}},"alternative-id":["10.1002\/pssc.200983733"],"URL":"https:\/\/doi.org\/10.1002\/pssc.200983733","archive":["Portico"],"relation":{},"ISSN":["1862-6351","1610-1642"],"issn-type":[{"value":"1862-6351","type":"print"},{"value":"1610-1642","type":"electronic"}],"subject":[],"published":{"date-parts":[[2010,6,10]]}}}